Ginkgo biloba trees are widely planted in urban areas of developed countries for their resilience, longevity and aesthetic appeal. Annual pruning to control tree size, shape and interference with traffic and pedestrians generates large volumes of unutilized Ginkgo biomass. This study aimed to valorize these pruning residues into charcoal by optimizing pyrolysis conditions and evaluating its fuel properties. The pyrolysis experiment was conducted at 400 to 600 degrees Celsius, after oven drying pretreatment. The mass yield of charcoal was found to vary from 27.33 to 32.05 percent and the approximate volume shrinkage was found to be 41.19 to 49.97 percent. The fuel properties of the charcoals were evaluated using the moisture absorption test, proximate and ultimate analysis, thermogravimetry, calorimetry and inductively coupled plasma optical emission spectrometry. The calorific value improved from 20.76 to 34.26 MJ per kg with energy yield up to 46.75 percent. Charcoal exhibited superior thermal stability and better combustion performance. The results revealed satisfactory properties compared with other biomass, coal and biochar standards. The product complied with first grade stand
Radon-222 is a limiting background in many leading dark matter and low energy neutrino experiments. One way to mitigate Radon-222 is to fill external experimental components with a clean cover gas such as N2. At the SNOLAB facility in Canada, the 222Rn concentration in the cover gas systems of the experiments are monitored using a radon assay board developed by the SNO collaboration. To improve the sensitivity of N2 assays, a new trapping mechanism based on activated charcoal has been developed. The trap was purified and tested at SNOLAB. The methods for determining the efficiency, background, and sensitivity of the trap were described. Additionally, as part of the efficiency measurement, a radon calibration source was developed and characterized.
Lake sediment charcoal records are used in paleoecological analyses to reconstruct fire history including the identification of past wildland fires. One challenge of applying sediment charcoal records to infer fire history is the separation of charcoal associated with local fire occurrence and charcoal originating from regional fire activity. Despite a variety of methods to identify local fires from sediment charcoal records, an integrated statistical framework for fire reconstruction is lacking. We develop a Bayesian point process model to estimate probability of fire associated with charcoal counts from individual-lake sediments and estimate mean fire return intervals. A multivariate extension of the model combines records from multiple lakes to reduce uncertainty in local fire identification and estimate a regional mean fire return interval. The univariate and multivariate models are applied to 13 lakes in the Yukon Flats region of Alaska. Both models resulted in similar mean fire return intervals (100-350 years) with reduced uncertainty under the multivariate model due to improved estimation of regional charcoal deposition. The point process model offers an integrated statistic
Expansive soils such as Black Cotton Soils (BCS) present significant challenges for road subgrade construction due to their high plasticity, swelling potential, and low strength. This study explores a triphasic stabilization method using Bamboo Charcoal (BC), Quarry Dust (QD), and Lime (L) to enhance the engineering properties of BCS for rural road applications. Initial soil characterization involved standard tests, including Atterberg limits, compaction, and Californian Bearing Ratio (CBR) assessments. The soil was treated with varying BC proportions (5% to 35% at 5% intervals) in the initial phase, leading to a progressive reduction in the Plasticity Index (PI) and swell index and an enhancement in the CBR up to 20% BC content. This further resulted in a soaked CBR value of 2.7%. In the second phase, additional treatment combined with BC and QD, incorporating diverse QD proportions (4% to 24%) relative to the optimal BC content. This further improved the CBR to 7.7% at 12% QD, but the PI exhibited a non-linear trend. Finally, 5% lime was introduced in the final phase. This minimized the PI to 11.2% and significantly increased the CBR to 19%. The optimal combination of 20% BC, 12%
Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide (CO2) with the aim to avoid dangerous climate change. In this paper, we propose a simple mathematical model (a coupled system of nonlinear ODEs) to capture some of the dynamical effects produced by adding charcoal to fertile soils. The main goal is to understand to which extent charcoal is able to lock up carbon in soils. Our results are preliminary in the sense that we do not solve the CO2 sequestration problem. Instead, we do set up a flexible modeling framework in which the interaction between charcoal and soil can be tackled by means of mathematical tools. We show that our model is well-posed and has interesting large-time behaviour. Depending on the reference parameter range (e.g. type of soil) and chosen time scale, numerical simulations suggest that adding charcoal typically postpones the release of CO2.
The continuous emanation of radon due to trace amounts of uranium and thorium in detector materials introduces radon to the active detection volume of low-background rare event search detectors. $^{222}$Rn produces a particularly problematic background in the physics region of interest by the ``naked'' beta decay of its $^{214}$Pb daughter nucleus. While charcoal-based adsorption traps are expected to be effective for radon reduction in auxiliary circulation loops that service the warm components of current {ton-scale} detectors at slow flow rates $(0.5-2\;SLPM)$, radon reduction in the entire circulation loop at high flow rates $\mathcal{O}({100s\;SLPM})$ is necessary to reach high sensitivity in future generation experiments. In this article we explore radon dynamics with a charcoal-based radon reduction system in the main circulation loop of time projection chamber detectors. We find that even for perfect radon traps, circulation speeds of $2,000\;SLPM$ are needed to reduce radon concentration in a 10\,ton detector by 90\%. This is faster by a factor of four than the highest circulation speeds currently achieved in dark matter detectors. We further find that the effectiveness of
The exploitation of using agro-industrial residues as the cherry stone to produce charcoal and activated carbon is very relevant nowadays due to the high demand of these materials and their environmental advantages. This work describes the methods to prepare charcoal from cherry stones (CS) using final heating temperature of 600 °C, with or without the application of an equal flow of nitrogen or air. The isothermal time has been of 2 hours, an adequate time to study carbonisation by varying the atmosphere. The charcoal obtained has the appropriate characteristics as precursors of activated carbon. Of the three samples prepared in different atmospheres, *N, N~ and AN, the third is an activated carbon. It is evidenced that the yield in material carbonaceous is somewhat lower when applying the nitrogen current and approximately 5% less when applying the air current. For the different samples, in this work we have studied the effects of the atmosphere during the heat treatment of CS, the yield, the chemical composition and the structure, as well as the pore structure of the same.
We report on an extensive characterization of the cracking noise produced by charcoal samples when dampened with ethanol. We argue that the evaporation of ethanol causes transient and irregularly distributed internal stresses that promote the fragmentation of the samples and mimic some situations found in mining processes. The results show that, in general, the most fundamental seismic laws ruling earthquakes (Gutenberg-Richter law, unified scaling law for the recurrence times, Omori's law, productivity law and Bath's law) hold under the conditions of the experiment. Some discrepancies were also identified (a smaller exponent in Gutenberg-Richter law, a stationary behavior in the aftershock rates for long times and a double power-law relationship in productivity law) and related to the different loading condition. Our results thus corroborate to elucidate the parallel between seismic laws and fracture experiments caused by a more complex loading condition that also occurs in natural and induced seismicity (such as long-term fluid injection and gas-rock outbursts in mining processes).
A new analysis has precisely dated paintings in France’s Font-de-Gaume cave for the first time。 Scientists discovered charcoal inside black pigments once thought to contain only minerals, allowing them to use radiocarbon dating。 The results show that a bison was painted about 13,000 years ago, while sections of a mask-like figure were added during
Charcoal rot is a fungal disease that thrives in warm dry conditions and affects the yield of soybeans and other important agronomic crops worldwide. There is a need for robust, automatic and consistent early detection and quantification of disease symptoms which are important in breeding programs for the development of improved cultivars and in crop production for the implementation of disease control measures for yield protection. Current methods of plant disease phenotyping are predominantly visual and hence are slow and prone to human error and variation. There has been increasing interest in hyperspectral imaging applications for early detection of disease symptoms. However, the high dimensionality of hyperspectral data makes it very important to have an efficient analysis pipeline in place for the identification of disease so that effective crop management decisions can be made. The focus of this work is to determine the minimal number of most effective hyperspectral bands that can distinguish between healthy and diseased specimens early in the growing season. Healthy and diseased hyperspectral data cubes were captured at 3, 6, 9, 12, and 15 days after inoculation. We utilize
By analysing the K2 short-cadence data from Campaign 14 we detect phase-curve modulation in the light curve of the hot-Jupiter host star WASP-104. The ellipsoidal modulation is detected with high significance and in agreement with theoretical expectations, while Doppler beaming and reflection modulations are detected tentatively. We show that the visual geometric albedo is lower than 0.03 at 95% confidence, making it one of the least-reflective planets found to date. The light curve also exhibits a rotational modulation, implying a stellar rotational period likely to be near 23 or 46 days. In addition, we refine the system parameters and place tight upper limits for transit timing and duration variations, starspot occultation events, and additional transiting planets.
Radon is one of the most important sources of background in rare event search experiments, such as those searching for Dark Matter and neutrinos, due to its unavoidable production from natural uranium. In low-background experiments, radon emanation from detector materials and components accounts for a major portion of contamination. To investigate this, a radon detection system was developed at the Carleton nOble Liquid Detector Laboratory (COLD Lab). The setup consists of a stainless steel emanation chamber, a low-background ZnS(Ag) cell, and an assembly for radon transfer and collection. This setup was used to study radon emanation from materials under vacuum conditions. Additionally, a charcoal trap made of activated charcoal and equipped with a flow meter was constructed to study radon levels in nitrogen gas and the residual radon in the gas filter used in the DEAP-3600 processing system. The radon concentration in the glove box, where critical DEAP-3600 internal detector components were completed, was also calculated based on these measurements. Now calibrated and in-use, the COLD lab radon emanation counter is an essential diagnostic tool for reducing backgrounds in future ra
We present the performance of an efficient radon trap using silver-zeolite Ag-ETS-10, measured with a spherical proportional counter filled with an argon/methane mixture. Our study compares the radon reduction capabilities of silver-zeolite and the widely used activated charcoal, both at room temperature. We demonstrate that silver-zeolite significantly outperforms activated charcoal by three orders of magnitude in radon capture. Given that radon is a major background contaminant in rare event searches, our findings highlight silver-zeolite as a highly promising adsorbent, offering compelling operational advantages for both current and future dark matter and neutrino physics experiments. Furthermore, this not only offers great promise for developing future radon reduction systems in underground laboratories, but also paves the way for innovative, multidisciplinary advancements with far-reaching implications in science, engineering and environmental health.
The NML cryogenic plant cools two individually cryostated superconducting radio frequency (SRF) capture cavities and one prototype ILC cryomodule with eight SRF cavities. This complex accelerates electrons at 150 MeV for the Integrable Optics Test Accelerator (IOTA) ring, located at the Fermilab Accelerator Science and Technology (FAST) facility. The cryogenic plant is composed of two nitrogen precooled Tevatron satellite refrigerators, two Mycom 2016C compressors, a cryogenic distribution system, a Frick purifier compressor, two charcoal bed adsorber purifiers, and a liquid ring vacuum pump with a roots booster. The SRF cavities are immersed in a 2.0 K liquid helium bath, shielded with a 5 K gaseous helium shield and a liquid nitrogen cooled thermal shield. Since 2019, this R&D accelerator complex has gone through four science runs with an average duration of 12 months. Operational experience for each run, availability metrics, performance data and common outages are presented in this paper.
The Full Flow Purifier for Fermilab's Muon Campus uses a charcoal bed surrounded by a liquid nitrogen jacket to purify up to 240 g/s of helium gas. Fabrication by Ability Engineering Technology Inc. has been completed and the purifier delivered to Fermilab. It is the largest purifier to be used at Fermilab based on both capacity and size. A previous paper discussed the design of purifier for various operational conditions and horizontal shipping. The purifier is designed to withstand 5g force in vertical and 2g force in lateral and longitudinal directions. Transportation experience from vendor to Fermilab and within site is discussed. Integration of the purifier involved design and fabrication of a liquid nitrogen transfer line, regeneration system, and helium piping to connect it to Muon Campus cryogenic system. It also involved establishing electrical, instrumentation and controls connections to the system. Integration of the purifier is discussed in detail. The purifier is to be commissioned using up to 4 MYCOM helium compressors to supply helium and liquid nitrogen supplied by a 60,000-liter tank. Actual effectiveness of the 3-stream heat exchanger is to be estimated based on m
Objective: In the framework of the Cometary Physics Laboratory (CoPhyLab) and its sublimation experiments of cometary surface analogues under simulated space conditions, we characterize the properties of intimate mixtures of juniper charcoal and SiO$_2$ chosen as a dust analogue \citep{Lethuillier_2022}. We present the details of these investigations for the spectrophotometric properties of the samples. Methods: We measured these properties using a hyperspectral imager and a radio-goniometer. From the samples' spectra, we evaluated reflectance ratios and spectral slopes. From the measured phase curves, we inverted a photometric model for all samples. Complementary characterizations were obtained using a pycnometer, a scanning electron microscope and an organic elemental analyser. Results: We report the first values for the apparent porosity, elemental composition, and VIS-NIR spectrophotometric properties for juniper charcoal, as well as for intimate mixtures of this charcoal with the SiO$_2$. We find that the juniper charcoal drives the spectrophotometric properties of the intimate mixtures and that its strong absorbance is consistent with its elemental composition. We find that S
Constant ingress of impurities in Muon Campus g-2 experiment at Fermilab has resulted in reduction of efficiency of cryogenic expanders and occasional undesired downtime to flush the impurities. Due to insufficiency of current 60 g/s mobile purifier, a full flow purifier is designed to be used in Muon Campus which purifies 240 g/s of Helium throughput of 4 compressors through charcoal bed at 80 K and returns ambient Helium back to the system. The purifier is designed to be operated near liquid Nitrogen temperature during cold operations and up to 400 K during regeneration. Both warm and cold operational range of the purifier has required use of appropriate clearances in design due to expansion and contraction. The vessel of around 16 ft height which is designed to be operated vertically is to be shipped horizontally. The asymmetrical position of heavy stainless steel heat exchanger in the purifier support frame and 5g vertical load design consideration for shipping has required use of shipping supports and heat exchanger rotational stops to comply with design requirements. FEA of purifier system is performed in cold, warm and shipping cases to verify that the purifier satisfies the
We introduce a new methodology 'charcoal' for estimating the location of sparse changes in high-dimensional linear regression coefficients, without assuming that those coefficients are individually sparse. The procedure works by constructing different sketches (projections) of the design matrix at each time point, where consecutive projection matrices differ in sign in exactly one column. The sequence of sketched design matrices is then compared against a single sketched response vector to form a sequence of test statistics whose behaviour shows a surprising link to the well-known CUSUM statistics of univariate changepoint analysis. The procedure is computationally attractive, and strong theoretical guarantees are derived for its estimation accuracy. Simulations confirm that our methods perform well in extensive settings, and a real-world application to a large single-cell RNA sequencing dataset showcases the practical relevance.
We have conducted precise magnetization measurements down to 0.5 K with a miniature 3He cryostat and a closed-cycle 3He gas handling system for a commercial superconducting quantum interference device magnetometer [Magnetic Property Measurement System (Quantum Design)]. The gas handling system contains two sorption pumps filled with granular charcoals. We pressurize 3He gas up to ambient pressure for the liquification at 3 K and then pump the vaper for cooling. The lowest sample temperature is ~ 0.5 K and it can persist for 34 hours. We demonstrate the performance of the system by observing the Meissner effect of aluminum below the superconducting transition temperature ~ 1 K. We also measured the magnetization curve of the heavy fermion superconductor CeCoIn5 resulting in successful observation of the lower critical field at 0.5 K.
The noble elements, argon and xenon, are frequently employed as the target and event detector for weakly interacting particles such as neutrinos and Dark Matter. For such rare processes, background radiation must be carefully minimized. Radon provides one of the most significant contaminants since it is an inevitable product of trace amounts of natural uranium. To design a purification system for reducing such contamination, the adsorption characteristics of radon in nitrogen, argon, and xenon carrier gases on various types of charcoals with different adsorbing properties and intrinsic radioactive purities have been studied in the temperature range of 190-295 K at flow rates of 0.5 and 2 standard liters per minute. Essential performance parameters for the various charcoals include the average breakthrough times ($τ$), dynamic adsorption coefficients (k$_a$) and the number of theoretical stages (n). It is shown that the k$_a$-values for radon in nitrogen, argon, and xenon increase as the temperature of the charcoal traps decreases, and that they are significantly larger in nitrogen and argon than in xenon gas due to adsorption saturation effects. It is found that, unlike in xenon, t