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Abstract Owing to the significant attention directed toward alloy metal nanoclusters, it is crucial to explore the relationship between their structures and their performance during the electrocatalytic CO 2 reduction reaction (eCO 2 RR) and discover potential synergistic effects for the design of novel functional nanoclusters. However, a lack of suitable analogs makes this investigation challenging. In this study, we synthesized a well‐defined pair of structural analogs, [Au 8 Cu 1 (SAdm) 4 (Dppm) 3 Cl] 2+ and [Au 8 Ag 1 (SAdm) 4 (Dppm) 3 Cl] 2+ ( Au 8 Cu 1 and Au 8 Ag 1 , respectively), and characterized them. Single‐crystal X‐ray diffraction analysis revealed that Au 8 M 1 (M=Cu/Ag) consists of a tetrahedral Au 3 M 1 core capped by three (Dppm)Au staples, one Au 2 (SR) 3 staple, one lone SR ligand, and a terminal Cl ligand. Ag and Cu were doped at the same site in the Au 8 M 1 nanoclusters, which has rarely been reported. Au 8 Cu 1 exhibited a significantly higher CO Faradaic efficiency (FE CO ; ~82.2 %) during eCO 2 RR than that of Au 8 Ag 1 (FE CO ; ~33.1 %). Density functional theory calculations demonstrated that *COOH is the key intermediate in the reduction of CO 2 to CO. The formation of *COOH on Au 8 Cu 1 is more thermodynamically stable than on Au 8 Ag 1 , and Au 8 Cu 1 shows a smaller *CO formation energy than that on Au 8 Ag 1 , which promotes the reduction of CO 2 . We believe that the structural analogs Au 8 Cu 1 and Au 8 Ag 1 offer a suitable template for the in‐depth investigation of structure‐property correlations at the atomic level.

We have investigated the impact of thermal annealing on the interaction of single layer MoS2 and Au using Raman Spectroscopy. We found MoS2 has two main modes of interactions with the underlying Au being either weakly-coupled or strongly-coupled. The regions strongly-coupled to Au are hybridized to Au, minimally strained, and electron-doped. The weakly-coupled regions are found to be slightly hole-doped with tensile strain of 1.0 %. The observed nanoscale inhomogeneities in doping would result in Au contacts having a large variability in performance. The overall areal coverage of the strongly-coupled regions is not increased by thermal annealing, and the variability in the degree of hybridization increases at annealing temperatures above 100 °C. Our data also show that monolayer MoS2 starts to decouple from Au around 100 °C, becoming fully decoupled above 250 °C, suggesting that monolayer MoS2 produced by Au-assisted mechanical exfoliation may be more easily transferred off Au at elevated temperatures.

Transverse momentum spectra of charged hadrons with ${p_{T} <}$ 6 GeV/c have been measured near mid-rapidity (0.2 $< η<$ 1.4) by the PHOBOS experiment at RHIC in Au + Au and d + Au collisions at ${\sqrt{s_{_{NN}}} = \rm {200 GeV}}$. The spectra for different collision centralities are compared to ${p + \bar{p}}$ collisions at the same energy. The resulting nuclear modification factor for central Au + Au collisions shows evidence of strong suppression of charged hadrons in the high-$p_{T}$ region (${>2}$ GeV/c). In contrast, the d + Au nuclear modification factor exhibits no suppression of the high-$p_{T}$ yields. These measurements suggest a large energy loss of the high-$p_{T}$ particles in the highly interacting medium created in the central Au + Au collisions. The lack of suppression in d + Au collisions suggests that it is unlikely that initial state effects can explain the suppression in the central Au + Au collisions.

The electronic structure of Au-Sn intermetallic layers of different compositions grown on Au(111) to the thickness of several nanometers has been studied in this work. The layer, interface and the substrate related components in the Au 4$f$ and Sn 4$d$ core-level spectra obtained using x-ray photoelectron spectroscopy (XPS) vary with deposition parameters to reveal the details of the Au-Sn formation. While AuSn is grown by deposition at room temperature, Au rich compounds form as a result of heat treatment through inter diffusion of Au and Sn. Deposition at high temperature forms more Au rich compositions compared to post annealing at the same temperature due to the kinetic energy of the impinging Sn atoms in the former case. Post annealing, on the other hand, stabilizes the bulk phases such as AuSn and Au$_5$Sn and exhibits an activated behavior for transition from the former to the latter with increasing temperature. The XPS valence band spectra of AuSn and Au$_{5}$Sn layers show good agreement with the density functional theory calculation, indicating that these have the bulk structure reported in literature. However, the influence of anti-site defects is observed in Au$_5$Sn. L

Bovine serum albumin-embedded Au nanoclusters (BSA-AuNCs) are thoroughly probed by continuous wave electron paramagnetic resonance (CW-EPR), light-induced EPR (LEPR), and sequences of microscopic investigations performed via high-resolution transmission electron microscopy (HR-TEM), scanning transmission electron microscopy (STEM), and energy dispersive X-ray analysis (EDS). To the best of our knowledge, this is the first report analyzing the BSA-AuNCs by CW-EPR/LEPR technique. Besides the presence of Au(0) and Au(I) oxidation states in BSA-AuNCs, the authors observe a significant amount of Au(II), which may result from a disproportionation event occurring within NCs: 2Au(I) → Au(II) + Au(0). Based on the LEPR experiments, and by comparing the behavior of BSA versus BSA-AuNCs under UV light irradiation (at 325 nm) during light off-on-off cycles, any energy and/or charge transfer event occurring between BSA and AuNCs during photoexcitation can be excluded. According to CW-EPR results, the Au nano assemblies within BSA-AuNCs are estimated to contain 6-8 Au units per fluorescent cluster. Direct observation of BSA-AuNCs by STEM and HR-TEM techniques confirms the presence of such diameters of gold nanoclusters in BSA-AuNCs. Moreover, in situ formation and migration of Au nanostructures are observed and evidenced after application of either a focused electron beam from HR-TEM, or an X-ray from EDS experiments.

Based on the observation of the long-lived isotopes 261Rg and 265Rg (Z = 111, t(1/2) >= 10^(8) y) in natural Au, an experiment was performed to enrich Rg in 99.999% Au. 16 mg of Au were heated in vacuum for two weeks at a temperature of 1127 deg. C (63 deg. C above the melting point of Au). The content of 197Au and 261Rg in the residue was studied with high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The residue of Au was 3x10^(-6) of its original quantity. The recovery of Rg was a few percent. The abundance of Rg compared to Au in the enriched solution was about 2x10^(-6), which is a three to four orders of magnitude enrichment. It is concluded that the evaporation rate of Rg from an Au matrix in vacuum at 63 deg. C above the Au melting point is lower than that of Au. This experiment reinforces our first observation of Rg in a terrestrial material. As before it is concluded that a long-lived isomeric state exists in 261Rg and that it probably belongs to a new class of isomeric states, namely high spin super- or hyperdeformed isomeric states.

We have investigated the superconducting critical temperatures of Nb/Au/CoFe trilayers as a function of Au and CoFe thicknesses. Without the CoFe layer the superconducting critical temperatures of Nb/Au bilayers as a function of Au thickness follow the well-known proximity effect between a superconductor and a normal metal. The superconducting critical temperatures of Nb/Au/CoFe trilayers as a function of Au thickness exhibit a rapid initial increase in the small Au thickness region and increase slowly to a limiting value above this region, accompanied by a small oscillation of Tc. On the other hand, the superconducting critical temperatures of Nb/Au/CoFe trilayers as a function of CoFe thickness show non-monotonic behavior with a shallow dip feature. We analyzed the Tc behavior in terms of Usadel formalism and found that most features are consistent with the theory, although the small oscillation of Tc as a function of the Au thickness cannot be accounted for. We have also found quantitative values for the two interfaces: Nb/Au and Au/CoFe.

We present {\it Hubble Space Telescope} Advanced Camera for Surveys multicolor coronagraphic images of the recently discovered edge-on debris disk around the nearby ($\sim10$ pc) M dwarf AU Microscopii. The disk is seen between $r = $0\farcs 75 -- 15'' (7.5 -- 150 AU) from the star. It has a thin midplane with a projected full-width-at-half-maximum (FWHM) thickness of 2.5 -- 3.5 AU within $r < 50$ AU of the star that increases to 6.5 -- 9 AU at $r \sim 75$ AU. The disk's radial brightness profile is generally flat for $r < 15$ AU, then decreases gradually ($I \propto r^{-1.8}$) out to $r \approx 43$ AU, beyond which it falls rapidly ($I \propto r^{-4.7}$). Within 50 AU the midplane is straight and aligned with the star, and beyond that it deviates by $\sim3^{\circ}$, resulting in a bowed appearance that was also seen in ground-based images. Three-dimensional modelling of the disk shows that the inner region ($r < 50$ AU) is inclined to the line-of-sight by $<1^{\circ}$ and the outer disk by $\sim3^{\circ}$. The inclination of the outer disk and moderate forward scattering ($g \approx 0.4$) can explain the apparent bow. The intrinsic, deprojected FWHM thickness is 1.5 --

The dynamical structure of the Kuiper belt beyond 50 au is not well understood. Here we report results of a numerical model with long-range, slow and grainy migration of Neptune. The model implies that bodies scattered outward by Neptune to semimajor axes a>50 au often evolve into resonances which subsequently act to raise the perihelion distances of orbits to q>40 au. The implication of the model is that the orbits with 50<a<100 au and q>40 au should cluster near (but not in) the resonances with Neptune (3:1 at a=62.6 au, 4:1 at a=75.9 au, 5:1 at a=88.0 au, etc.). The recent detection of several distant Kuiper Belt Objects (KBOs) near resonances is consistent with this prediction, but it is not yet clear whether the orbits are really non-resonant as our model predicts. We estimate from the model that there should presently be ~1600-2400 bodies at the 3:1 resonance and ~1000-1400 bodies at the 4:1 resonance (for q>40 au and diameters D>100 km). These results favorably compare with the population census of distant KBOs inferred from existing observations.

We report a combined microscopy and spectroscopy study of Au deposited on the Bi2Se3(0001) single crystal surface. At room temperature Au forms islands, according to the Volmer-Weber growth mode. Upon annealing to 100° C the Au deposits are not stable and assemble into larger and thicker islands. The topological surface state of Bi2Se3 is weakly affected by the presence of Au. Contrary to other metals, such as Ag or Cr, a strong chemical instability at the Au/Bi2Se3 interface is ruled out. Core level analysis highlights Bi diffusion toward the surface of Au islands, in agreement with previous findings, while chemical interaction between Au and atomic Se is limited at the interfacial region. For the investigated range of Au coverages, the Au/Bi2Se3 heterostructure is inert towards CO and CO2 exposure at low pressure (10-8 mbar) regime.

The first metallic glass of Au-Si alloy has been discovered for over half a century, but its atomic structure is still puzzling. Herein, Au 8 Si dodecahedrons with local five-fold symmetry are revealed as building blocks in Au-Si metallic glass, and the interconnection modes of Au 8 Si dodecahedrons determine the medium-range order. With dimensionality reduction, the surface ordering is attributed to the motif transformation of Au 8 Si dodecahedrons into planar Au 5 Si pyramids with five-fold symmetry, and thus the self-assembly of Au 5 Si pyramids leads to the formation of the ordered Au 2 Si monolayer with the lowest energy. Furthermore, the structural similarity analysis is performed to unveil the physical origin of structural characteristics in different dimensions. The amorphism of Au-Si is due to the smooth energy landscape around the global minimum, while the ordered surface structure occurs due to the steep energy landscape.

We have used scanning tunneling microscopy to study the structure of graphene islands on Au(111) grown by deposition of elemental carbon at 950°C. Consistent with low-energy electron microscopic observations, we find that the graphene islands have dendritic shapes. The islands tend to cover depressed regions of the Au surface, suggesting that Au is displaced as the graphene grows. If small tunneling currents are used, it is possible to image simultaneously the graphene/Au moiré and the Au herringbone reconstruction, which forms underneath the graphene on cooling from the growth temperature. The delicate herringbone structure and its periodicity remain unchanged from the bare Au surface. Using a Frenkel-Kontorova model we deduce that this striking observation is consistent with an attraction between graphene and Au of less than 13 meV per C atom. Raman spectroscopy supports this weak interaction. However, at the tunneling currents necessary for atomic resolution image of graphene, the Au reconstruction is altered, implying influential tip-sample interactions and a mobile Au surface beneath the graphene.

Local density fluctuations near the QCD critical point can be probed by intermittency analysis of scaled factorial moments in relativistic heavy-ion collisions. We report the first measurement of intermittency for charged particles in Au + Au collisions at $\sqrt{s_\mathrm{NN}}$ = 7.7-200 GeV from the STAR experiment at RHIC. We observe scaling behaviors in central Au + Au collisions, with the extracted scaling exponent decreasing from mid-central to the most central Au + Au collisions. Furthermore, the scaling exponent exhibits a non-monotonic energy dependence with a minimum around $\sqrt{s_\mathrm{NN}}$ = 20-30 GeV in central Au + Au collisions.

Much of the work on automatic facial expression recognition relies on databases containing a certain number of emotion classes and their exaggerated facial configurations (generally six prototypical facial expressions), based on Ekman's Basic Emotion Theory. However, recent studies have revealed that facial expressions in our human life can be blended with multiple basic emotions. And the emotion labels for these in-the-wild facial expressions cannot easily be annotated solely on pre-defined AU patterns. How to analyze the action units for such complex expressions is still an open question. To address this issue, we develop a RAF-AU database that employs a sign-based (i.e., AUs) and judgement-based (i.e., perceived emotion) approach to annotating blended facial expressions in the wild. We first reviewed the annotation methods in existing databases and identified crowdsourcing as a promising strategy for labeling in-the-wild facial expressions. Then, RAF-AU was finely annotated by experienced coders, on which we also conducted a preliminary investigation of which key AUs contribute most to a perceived emotion, and the relationship between AUs and facial expressions. Finally, we prov

We present the discovery of a circumstellar dust disk surrounding AU Microscopium (AU Mic, GJ 803, HD 197481). This young M star at 10 parsec has the same age and origin as beta Pictoris, another nearby star surrounded by a dust disk. The AU Mic disk is detected between 50 AU and 210 AU radius, a region where dust lifetimes exceed the present stellar age. Thus, AU Mic is the nearest star where we directly observe the solid material required for planet formation. Since 85% of stars are M-type, the AU Mic disk provides new clues on how the majority of planetary systems might form and evolve.

Anisotropic Au nanoparticles show unique localized surface plasmon resonance (LSPR) properties, which make it attractive in optical, sensing, and biomedical applications. In this contribution, we report a general and facile strategy towards aqueous synthesis of Au and M@Au (M = Pd, CuPt) hybrid nanostars by reducing HAuCl4 with ethanolamine in the presence of cetyltrimethylammonium bromide (CTAB). According to electron microscopic observation and spectral monitoring, we found that the layered epitaxial growth mode (i.e., Frank-van der Merwe mechanism) contributes to the enlargement of the core, while, the random attachment of Au nanoclusters onto the cores accounts for the formation of the branches. Both of them are indispensable for the formation of the nanostars. The LSPR properties of the Au nanoparticles have been well investigated with morphology control via precursor amount and growth temperature. The Au nanostars showed improved surface-enhanced Raman spectroscopy (SERS) performance for rhodamine 6G due to their sharp edges and tips, which were therefore confirmed as good SERS substrate to detect trace amount of molecules.

We report the first observation of the reactions $Au + Au \to Au + Au + ρ^0$ and $Au + Au \to Au^* + Au^* + ρ^0$ with the STAR detector. The $ρ$ are produced at small perpendicular momentum, as expected if they couple coherently to both nuclei. We discuss models of vector meson production and the correlation with nuclear breakup, and present a fundamental test of quantum mechanics that is possible with the system.