Rotationally resolved spectra of the HNC$^+$ and HCN$^+$ molecular ions have been recorded in the spectral range between 6200 and 6800 \rcm\ using a cryogenic ion trap instrument. The rovibrational transitions were probed using two different action spectroscopy schemes, namely laser-induced reaction (LIR) and leak-out spectroscopy (LOS). Various vibrational bands of HNC$^+$ and HCN$^+$ were measured with high resolution for the first time. For HNC$^+$, the $\text{X}~^2Σ^+~(20^00)-(00^00)$ overtone band was recorded using LIR, while LOS was used to probe the $\text{X}~^2Π~(000)^1-(210)^0μ$ combination band and the $\text{X}~^2Π~(000)^1-\text{A}~^2Σ^+~(10^00)$ vibronic band of HCN$^+$. Spectroscopic constants, band origins and radiative lifetimes for the observed states have been determined. The effective fit for the HCN$^+$ spectra revealed the presence of strong vibrational couplings leading to perturbations of the rovibrational levels of the excited states. The two action spectroscopy schemes are compared and their potential use to explore ion-molecule interactions is discussed.
The BESIII collaboration has collected large data samples in the center-of-mass energy range from 1.84 to 4.95 GeV. These data provide a low-background environment and suitable phase space for studying the spectroscopy of light baryons. In this article, we review the achievements of baryon spectroscopy studies by the BESIII collaboration. Most of the results are obtained through the partial wave analysis (PWA) method, with spin and parity well determined.
To meet the challenges of high-resolution molecular spectroscopy, increasingly sophisticated spectroscopic techniques were developed. For a long time FTIR and laser-based spectroscopies were used for these studies. The recent development of dual-comb spectroscopy at high-resolution makes this technique a powerful tool for gas phase studies. We report on the use and characterization of the IRis-F1, a tabletop mid-infrared dual-comb spectrometer, in the newly developed step-sweep mode. The resolution of the wavenumber axis is increased by step-wise tuning (interleaving) and accurate measurement of the laser center wavelength and repetition frequency. Doppler limited measurements of N2O and CH4 reveal a wavenumber accuracy of 1E-4 cm-1 on the covered range of > 50 cm-1. Measured half-widths of absorption lines show no systematic broadening, indicating a negligible instrument response function. Finally, measurements of nitrogen pressure broadening coefficients in the v4 band of methane show that quantum cascade laser dual-comb spectroscopy in step-sweep mode is well adapted for measurements of precision spectroscopic data, in particular line shape parameters.
The understanding of the formation and evolution of the solar system still has many unanswered questions. Formation of solids in the solar system, mineral and organic mixing, and planetary body creation are all topics of interest to the community. Studying these phenomena is often performed through observations, remote sensing, and in-situ analysis, but there are limitations to the methods. Limitations such as IR diffraction limits, spatial resolution issues, and spectral resolution issues can prevent detection of organics, detection and identification of cellular structures, and the disentangling of granular mixtures. Optical-PhotoThermal InfraRed (O-PTIR) spectroscopy is a relatively new method of spectroscopy currently used in fields other than planetary sciences. O-PTIR is a non-destructive, highly repeatable, and fast form of measurement capable of reducing these limitations. Using a dual laser system with an IR source tuned to the mid-IR wavelength we performed laboratory O-PTIR measurements to compare O-PTIR data to existing IR absorption data and laboratory FTIR measurements for planetary materials. We do this for the purpose of introducing O-PTIR to the planetary science c
We present a concise report on the '2DHybrid' method, an innovative extension of two-dimensional correlation spectroscopy (2D COS), tailored for quasar light curve analysis. Addressing the challenge of discerning periodic variations against the background of intrinsic "red" noise fluctuations, this method employs cross-correlation of wavelet transform matrices to reveal distinct correlation patterns between underlaying oscillations, offering new insights into quasar dynamics.
Signal-to-noise ratio optimization, regarding repetition time selection, was explored mathematically and experimentally for single-voxel proton magnetic resonance spectroscopy. Theoretical findings were benchmarked against phantom measurements at 1.5 Tesla and localized in vivo proton brain spectra acquired at both 1.5 Tesla/3.0 Tesla. A detailed mathematical description of signal-to-noise ratio per unit time was derived, yielding an optimal repetition time of 1.256 times the metabolite longitudinal relaxation time. While long-repetition-time acquisitions minimize longitudinal relaxation time contributions, a repetition time of ~1.5s results in maximum signal-to-noise ratio per unit time, which can in turn be invested into smaller voxel sizes. The latter is of utmost importance in brain oncology, allowing accurate spectroscopic characterization of small lesions.
Thermal X-ray spectra from supernova remnants (SNRs) are dominated by a number of line emission from various elements. Resolving the individual lines is critically important for a variety of scientific topics such as diagnosing high-temperature and low-density non-equilibrium plasmas, identifying spectral features like charge exchange and resonance line scattering, revealing kinematics and elemental abundances of SN ejecta and the circumstellar medium, and studying the interstellar medium or planets' atmospheres from extinction features seen in X-ray spectra of very bright SNRs. This chapter reviews high-resolution X-ray spectroscopy of SNRs obtained so far. Most results were derived with dispersive spectrometers aboard Einstein, Chandra, and XMM-Newton satellites. Because these dispersive spectrometers were slitless, one has to select small objects with angular sizes less than a few arcminutes to successfully perform high-resolution spectroscopy. Despite this limitation, the three satellites delivered fruitful scientific results in the last few decades. Arrays of low-temperature microcalorimeters offer excellent opportunities for high-resolution X-ray spectroscopy of SNRs, as they
Integral field, or 3D, spectroscopy is the technique of obtaining spectral information over a two-dimensional, hopefully contiguous, field of view. While there is some form of astronomical 3D spectroscopy at all wavelengths, there has been a rapid increase in interest in optical and near-infrared 3D spectroscopy. This has resulted in the deployment of a large variety of integral-field spectrographs on most of the large optical/infrared telescopes. The amount of IFU data available in observatory archives is large and growing rapidly. The complications of treating IFU data as both imaging and spectroscopy make it a special challenge for the virtual observatory. This article describes the various techniques of optical and near-infrared spectroscopy and some of the general needs and issues related to the handling of 3D data by the virtual observatory.
I discuss how spectroscopy of extragalactic globular clusters provides a powerful probe of the formation history and mass distribution of galaxies. One critical area is spectroscopy of objects which have been identified as candidate young globular clusters through HST imaging of galaxy mergers. I discuss how such data can constrain models of globular cluster and galaxy formation. As an example, I present new spectra which confirm the presence of young globular clusters in NGC 1275. A second way wide-field spectroscopy can be used to probe the formation history and mass distribution of galaxies is through spectroscopy of large numbers of globular clusters around elliptical galaxies. Metallicities obtained from such data place strong constraints on models of galaxy formation, and velocities determined from the same data provide kinematical tracers of the mass distribution out to distances of $\sim 100$ kpc.
We propose an on-chip mid-infrared (MIR) photonic spectroscopy platform for aerosol characterization to obtain highly discriminatory information on the chemistry of aerosol particles. Sensing of aerosols is crucial for various environmental, climactic, warfare threat detection, and pulmonary healthcare applications. Further, there are a number of unintended situations for potential exposure to bioaerosols such as viruses, bacteria, and fungi. For instance, the current pandemic scenario of COVID-19 occurring across the world. Currently, chemical characterization of aerosols is performed using FTIR spectroscopy yielding chemical fingerprinting because most of the vibrational and rotational transitions of chemical molecules fall in the MIR range; and Raman spectroscopy. Both techniques use free space bench-top geometries. Here, we propose miniaturized on-chip MIR photonics-based aerosol spectroscopy consisting of a broadband spiral-waveguide sensor that significantly enhances particle-light interaction to improve sensitivity. The spiral waveguides are made of a chalcogenide glass material (Ge23Sb7S70) which shows a broad transparency over IR range. We demonstrate the sensing of N-meth
Impedance Spectroscopy resolves electrical properties into uncorrelated variables, as a function of frequency, with exquisite resolution. Separation is robust and most useful when the system is linear. Impedance spectroscopy combined with appropriate structural knowledge provides insight into pathways for current flow, with more success than other methods. Biological applications of impedance spectroscopy are often not useful since so much of biology is strongly nonlinear in its essential features, and impedance spectroscopy is fundamentally a linear analysis. All cells and tissues have cell membranes and its capacitance is both linear and important to cell function. Measurements proved straightforward in skeletal muscle, cardiac muscle, and lens of the eye. In skeletal muscle, measurements provided the best estimates of the predominant (cell) membrane system that dominates electrical properties. In cardiac muscle, measurements showed definitively that classical microelectrode voltage clamp could not control the potential of the predominant membranes, that were in the tubular system separated from the extracellular space by substantial distributed resistance. In the lens of the eye
A comparison of the most popular techniques for 3D spectroscopy is presented in a way which should hopefully be useful for astronomers intending to use these techniques. Integral field spectroscopy, slitless spectroscopy, tunable imaging filters, imaging Fourier transform spectroscopy, and energy-resolving detectors are included in their different implementation. Their relative advantages and disadvantages are discussed in view of the possible scientific application.
Rotational transitions of $iso$-propyl cyanide, (CH$_3$)$_2$CHCN, also known as $iso$-butyronitrile, were recorded using long-path absorption spectroscopy in selected regions between 37 and 600 GHz. Further measurements were carried out between 6 and 20 GHz employing Fourier transform microwave (FTMW) spectroscopy on a pulsed molecular supersonic jet. The observed transitions reach $J$ and $K_a$ quantum numbers of 103 and 59, respectively, and yield accurate rotational constants as well as distortion parameters up to eighth order. The $^{14}$N nuclear hyperfine splitting was resolved in particular by FTMW spectroscopy yielding spin-rotation parameters as well as very accurate quadrupole coupling terms. In addition, Stark effect measurements were carried out in the microwave region to obtain a largely revised $c$-dipole moment component and to improve the $a$-component. The hyperfine coupling and dipole moment values are compared with values for related molecules both from experiment and from quantum chemical calculations.
We present a complex-valued electric field model for experimentally observed cavity transmission in coherent cavity-enhanced (CE) multiplexed spectroscopy (i.e., dual-comb spectroscopy, DCS). The transmission model for CE-DCS differs from that previously derived for Fourier-transform CE direct frequency comb spectroscopy [Foltynowicz et al., Appl. Phys. B 110, 163-175 (2013)] by the treatment of the local oscillator which, in the case of CE-DCS, does not interact with the enhancement cavity. Validation is performed by measurements of complex-valued near-infrared spectra of CO and CO$_2$ by an electro-optic frequency comb coherently coupled to an enhancement cavity of finesse $F=19600$. Following validation, we measure the $30012\leftarrow00001$ $^{12}$C$^{16}$O$_2$ vibrational band origin with a combined standard uncertainty of 770 kHz (fractional uncertainty of $4\times10^{-9}$).
Since 2014, MUSE, the Multi-Unit Spectroscopic Explorer, is in operation at the ESO-VLT. It combines a superb spatial sampling with a large wavelength coverage. By design, MUSE is an integral-field instrument, but its field-of-view and large multiplex make it a powerful tool for multi-object spectroscopy too. Every data-cube consists of 90,000 image-sliced spectra and 3700 monochromatic images. In autumn 2014, the observing programs with MUSE have commenced, with targets ranging from distant galaxies in the Hubble Deep Field to local stellar populations, star formation regions and globular clusters. This paper provides a brief summary of the key features of the MUSE instrument and its complex data reduction software. Some selected examples are given, how multi-object spectroscopy for hundreds of continuum and emission-line objects can be obtained in wide, deep and crowded fields with MUSE, without the classical need for any target pre-selection.
We have been undertaking a programme on the Gemini 8-m telescopes to demonstrate the power of integral field spectroscopy, using the optical GMOS spectrograph, and the new CIRPASS instrument in the near-infrared. Here we present some preliminary results from 3D spectroscopy of extra-galactic objects, mapping the emission lines in a 3CR radio galaxy and in a gravitationally lensed arc, exploring dark matter sub-structure through observations of an Einstein Cross gravitational lens, and the star formation time-scales of young massive clusters in the starburst galaxy NGC 1140.
We present two new types of spectroscopy methods for cold and ultra-cold neutrons. The first method, which uses the \RB drift effect to disperse charged particles in a uniformly curved magnetic field, allows to study neutron $β$-decay. We aim for a precision on the 10$^{-4}$ level. The second method that we refer to as gravity resonance spectroscopy (GRS) allows to test Newton's gravity law at short distances. At the level of precision we are able to provide constraints on any possible gravity-like interaction. In particular, limits on dark energy chameleon fields are improved by several orders of magnitude.
High-resolution X-ray spectroscopy has addressed not only various topics in coronal physics of stars, but has also uncovered important features relevant for our understanding of stellar evolution and the stellar environment. I summarize recent progress in coronal X-ray spectroscopy and in particular also discuss new results from studies of X-rays from pre-main sequence stars.
We demonstrate a high-performance apertureless near-field probe made of a tapered metal tip with a set of periodic shallow grooves near the apex. The spontaneous emission from a single emitter near the tip is investigated systematically for the side-illumination tip enhanced spectroscopy (TES). In contrast with the bare tapered metal tip in conventional side-illumination TES, the corrugated probe not only enhances strongly local excitation field but also concentrates the emission directivity, which leads to high collection efficiency and signal-to-noise ratio. In particular, we propose an asymmetric TES tip based on two coupling nanorods with different length at the apex to realize unidirectional enhanced emission rate from a single emitter. Interestingly, we find that the radiation pattern is sensitive to the emission wavelength and the emitter positions respective to the apex, which can result in an increase of signal-to-noise ratio by suppressing undesired signal. The proposed asymmetrical corrugated probe opens up a broad range of practical applications, e.g. increasing the detection efficiency of tip enhanced spectroscopy at the single-molecule level.
We report the observation and systematic investigation of the space charge effect and mirror charge effect in photoemission spectroscopy. When pulsed light is incident on a sample, the photoemitted electrons experience energy redistribution after escaping from the surface because of the Coulomb interaction between them (space charge effect) and between photoemitted electrons and the distribution of mirror charges in the sample (mirror charge effect). These combined Coulomb interaction effects give rise to an energy shift and a broadening which can be on the order of 10 meV for a typical third-generation synchrotron light source. This value is comparable to many fundamental physical parameters actively studied by photoemission spectroscopy and should be taken seriously in interpreting photoemission data and in designing next generation experiments.