The upper atmospheres of temperate sub-Neptunes are strongly influenced by atmospheric dynamics due to their cool equilibrium temperature and thereby longer chemical timescales than the atmospheric dynamical timescales. In this study, we used a three-dimensional (3D) general circulation model to investigate the transport-induced disequilibrium chemistry and vertical mixing on temperate gas-rich mini-Neptunes, using K2-18b as an example. We model K2-18b assuming 180 times solar metallicity and consider it as either a synchronous or an asynchronous rotator, exploring spin-orbit resonances of 2:1, 6:1, and 10:1. We find that the vertical transport affects the chemical structure significantly, making CO$_2$ and CO more abundant ($\sim$10$^{-3}$) in the upper atmosphere compared to the chemical equilibrium abundance (<10$^{-15}$), and horizontal winds further homogenize the chemical composition zonally in this region. Molecular abundances in the photosphere generally agree across different rotation periods. We employ a passive tracer in the model to estimate the one-dimensional (1D) equivalent eddy-diffusion coefficient ($K_{zz}$) of K2-18b, providing a parameter useful for future 1D
We report the first unambiguous detection of cannabinoid molecules in an exoplanetary atmosphere. Using 420 hours of JWST observations combining NIRSpec and MIRI instruments, we identify spectroscopic signatures of tetrahydrocannabinol (THC; $Δ^9$-C$_{21}$H$_{30}$O$_2$) and cannabidiol (CBD; C$_{21}$H$_{30}$O$_2$) in the transmission spectrum of the temperate sub-Neptune K2-18b. The THC feature at 2.42~$μ$m is detected at 9.2$σ$ significance, while CBD absorption at 3.69~$μ$m reaches 7.8$σ$. We additionally report a mysterious feature at exactly 4.20~$μ$m detected at 4.20$σ$ (the probability of this coincidence is discussed extensively). Our atmospheric retrievals using the novel \texttt{TerpeneRetrieval} code indicate a CBD-to-THC ratio of 0.40$\pm$0.08, classifying K2-18b as a ``balanced hybrid'' world according to standard terrestrial cannabis taxonomy. We introduce the Cannabis Habitable Zone (``Green Zone'') framework and demonstrate that K2-18b lies squarely within it. We explore multiple production mechanisms including biogenic synthesis, abiotic photochemistry, exogenous delivery via ``space nuggets,'' and deliberate atmospheric engineering by an advanced civilization. Thes
K2-18b closely orbits a nearby M3 dwarf within its habitable zone, where this planet could be either a super-Earth or a mini-Neptune. Recent studies using transit spectroscopy suggest that it is Hycean in nature, but this classification is currently controversial. We use the N-body integrator rebound and its extension library reboundx to investigate the possibility of exomoons around K2-18b. Due to tidal interactions that induce outward migration, we find that any moons would be extremely unlikely. If formed, their lifetimes would be relatively short, not exceeding 10 Myr assuming Earth-like or Neptune-like tidal parameters for K2-18b. Recent studies estimate the stellar (and system) lifetime as 3 Gyr, which is significantly longer than the tidal migration timescale. We show that exomoons are unlikely to survive around K2-18b due to rapid tidal-driven migration, casting doubt on moon-based habitability scenarios for short-period M-dwarf planets in general.
The nature of the sub-Neptune K2-18b is debated between Hycean and mini-Neptune interpretations. We test whether self-consistent Hycean atmospheres are compatible with current JWST transmission spectra by combining one-dimensional photochemical modelling, radiative--convective equilibrium calculations, and forward modelling of transmission spectra. We assume H2-CH4-H2O atmospheres over a liquid ocean, compute altitude-dependent abundances with a 1D photochemical model, and couple them to P-T profiles that avoid runaway greenhouse states. Using the CH4-dominated 2.8-4.0 $μ$m band, we constrain wavelength-independent offsets between NIRISS SOSS and NIRSpec G395H for multiple reductions, and then scan grids of CO and CO2 scaling factors, weighted by the CH4-band offset posteriors, to evaluate oxidised-carbon abundances consistent with the 4-5 $μ$m region. Radiative--convective calculations further map pressures and albedos that yield non-runaway climates. Over a wide range of temperatures and pressures, liquid oceans can exist, and Hycean models with a 1 bar H2 envelope, percent-level CH4 and CO, and CO2 buffered at $\sim 10^{-3}$-$10^{-2}$ reproduce the NIRISS and NIRSpec spectra fro
K2-18b, a temperate sub-Neptune, has garnered significant attention due to claims of possible biosignatures in its atmosphere. Low-confidence detections of dimethyl sulfide (DMS) and/or dimethyl disulfide (DMDS) have sparked considerable debate, primarily around arguments that their absorption features are not uniquely identifiable. Here, we consider all five questions from the astrobiology standards of evidence framework, starting with: Have we detected an authentic signal? To answer this, we analyzed publicly-available JWST observations of K2-18b using independent data reduction and spectral retrieval methodologies. Our comprehensive set of reductions demonstrates that the MIRI transit spectrum is highly susceptible to unresolved instrumental systematics. Applying different wavelength binning schemes yields a potpourri of planet spectra that then lead to a wide assortment of atmospheric interpretations. Consequently, we offer recommendations to help minimize this previously-underappreciated instrument systematic in future MIRI reductions of any exoplanet. While the MIRI binning scheme adopted by Madhusudhan et al. (2025) favors the presence of DMS/DMDS in K2-18b, we find that 87.
K2-18b, a sub-Neptune exoplanet located in the habitable zone of its host star, has emerged as an important target for atmospheric characterization and assessments of potential habitability. Motivated by recent interpretations of JWST observations suggesting a hydrogen-rich atmosphere consistent with Hycean-world scenarios, we conducted a coordinated, multi-epoch search for narrowband radio technosignatures using the Karl G. Jansky Very Large Array equipped with the COSMIC backend and the MeerKAT telescope with the BLUSE backend. Our observations span frequencies from 544MHz to 9.8GHz and include multiple epochs that cover at least one full orbital period of the planet. In this work, we outline, create, and apply a comprehensive post-processing framework that incorporates observatory-informed RFI masking, drift-rate filtering based on the expected dynamics of the K2-18 system, multibeam spatial discrimination, primary and secondary transit filtering (when applicable), and SNR-based excision of weak and strong spurious signals. Across all bands and epochs, no signals consistent with an astrophysical or artificial origin were identified at a limit of 10^12 to 10^13W. These non-detect
K2-18b lies near the radius valley that separates super-Earths and sub-Neptunes, marking a key transitional regime in planetary and atmospheric composition. The system offers a valuable opportunity to study how M-dwarf high-energy stellar radiation influences atmospheric stability and the potential for sustaining volatile species, especially important in the context of the upcoming ELT and its ANDES spectrograph. This study characterizes the high-energy environment of K2-18 with X-ray observations from eROSITA, the soft X-ray instrument on the Spectrum-Roentgen-Gamma (SRG) mission, Chandra, and XMM-Newton. We derive a representative 0.2-2 keV X-ray flux with an APEC thermal plasma model fitted with the Bayesian X-ray Analysis (BXA). With the observed X-ray flux from the exoplanet host star, we estimate the photoevaporative mass loss of exoplanet K2-18b using the energy-limited model. In addition, we examine the thermal structure of the system based on a hydrodynamic model. In 100 ks XMM-Newton observation we identified K2-18 as a very faint X-ray source with $\mathrm{F_X = 10^{-15}\ erg\,s^{-1}\,cm^{-2}}$, with an activity level of (Lx/Lbol) $\sim 10^{-5}$. A small flare has been d
K2-18b, a sub-Neptune orbiting in the habitable zone of an M dwarf, has attracted significant interest following observations with the Hubble Space Telescope (HST) and, more recently, with the James Webb Space Telescope (JWST), which reveal detectable atmospheric features across the near- and mid-infrared. Using free-chemistry Bayesian retrievals, we investigate whether hydrocarbon hazes can explain the apparent mismatch of spectral feature amplitudes between the JWST NIRISS/NIRSpec and MIRI LRS datasets. We additionally assess the impact of stellar parameter uncertainties on the derived bulk properties of the planet and explore how planetary mass uncertainties affect atmospheric retrievals. We find that hazy scenarios can reproduce the combined JWST spectrum and provide a consistent explanation for the reduced NIRISS/NIRSpec feature amplitudes relative to the stronger MIRI features. Across all retrievals, the atmosphere remains consistent with an H$_2$-dominated sub-Neptune, with CH$_4$ and CO$_2$ as the dominant absorbers. Our hazy models retrieve systematically lower molecular abundances compared to haze-free models, reflecting the degeneracy between haze opacity and mean molecu
Mildly irradiated mini-Neptunes have densities potentially consistent with them hosting substantial liquid water oceans (`Hycean' planets). The presence of CO2 and simultaneous absence of ammonia (NH3) in their atmospheres has been proposed as a fingerprint of such worlds. JWST observations of K2-18b, the archetypal Hycean, have found the presence of CO2 and the depletion of NH3 to <100 ppm; hence, it has been inferred that this planet may host liquid water oceans. In contrast, climate modelling suggests that many of these mini-Neptunes, including K2-18b, may likely be too hot to host liquid water. We propose a solution to this discrepancy between observation and climate modelling by investigating the effect of a magma ocean on the atmospheric chemistry of mini-Neptunes. We demonstrate that atmospheric NH3 depletion is a natural consequence of the high solubility of nitrogen species in magma at reducing conditions; precisely the conditions prevailing where a thick hydrogen envelope is in communication with a molten planetary surface. The magma ocean model reproduces the present JWST spectrum of K2-18b to < 3 sigma, suggesting this is as credible an explanation for current obs
JWST recently measured the transmission spectrum of K2-18b, a habitable-zone sub-Neptune exoplanet, detecting CH$_4$ and CO$_2$ in its atmosphere. The discovery paper argued the data are best explained by a habitable "Hycean" world, consisting of a relatively thin H$_2$-dominated atmosphere overlying a liquid water ocean. Here, we use photochemical and climate models to simulate K2-18b as both a Hycean planet and a gas-rich mini-Neptune with no defined surface. We find that a lifeless Hycean world is hard to reconcile with the JWST observations because photochemistry only supports $< 1$ part-per-million CH$_4$ in such an atmosphere while the data suggest about $\sim 1\%$ of the gas is present. Sustaining %-level CH$_4$ on a Hycean K2-18b may require the presence of a methane-producing biosphere, similar to microbial life on Earth $\sim 3$ billion years ago. On the other hand, we predict that a gas-rich mini-Neptune with $100 \times$ solar metallicity should have 4% CH$_4$ and nearly 0.1% CO$_2$, which are compatible with the JWST data. The CH$_4$ and CO$_2$ are produced thermochemically in the deep atmosphere and mixed upward to the low pressures sensitive to transmission spectr
Determining the composition of an exoplanet atmosphere relies on the presence of detectable spectral features. The strongest spectral features, including DMS, look approximately Gaussian. Here, I perform a suite of Gaussian feature analyses to find any statistically significant spectral features in the recently published MIRI/LRS spectrum of K2-18b (N. Madhusudhan et al. 2025). In N. Madhusudhan et al. 2025, they claim a 3.4-$σ$ detection of spectral features compared to a flat line. In 5 out of 6 tests, I find the data preferred a flat line over a Gaussian model, with a $χ^{2}_ν$ of 1.06. When centering the Gaussian where the absorptions for DMS and DMDS peak, I find ln(B) = 1.21 in favour of the Gaussian model, with a $χ^{2}_ν$ of 0.99. With only $\sim$2-$σ$ in favour of Gaussian features, I conclude no strong statistical evidence for spectral features.
Quantifying disequilibria is important to understand whether an environment could be habitable. It has been proposed that the exoplanet K2-18b has a hydrogen-rich atmosphere and a water ocean, making it a "hycean world". The James Webb Space Telescope recently made measurements of methane, CO$_2$, and possibly dimethyl sulfide (DMS) in the atmosphere of this planet. The initial interpretation of these data is that they may support the occurrence of hycean conditions. Here, I attempt to take a next step in exploring the prospects for habitability. I use constraints on the abundances of atmospheric gases to calculate how much chemical disequilibrium there could be, assuming K2-18b is a hycean world. I find that the presence of oxidized carbon species coexisting with abundant H$_2$ (1-1000 bar) at cool to warm (25-120°C) conditions creates a strong thermodynamic drive for methanogenesis. More than ~75 kJ (mol C)$^{-1}$ of free energy can be released from CO$_2$ hydrogenation. Partially oxidized carbon compounds such as DMS (if present) also have potential to provide metabolic energy, albeit in smaller quantities. Because of the thermodynamic instability of CO$_2$ under hycean conditio
A recent observation of the exoplanet K2-18b sparked interest among scientists - large amounts of carbon dioxide and methane were detected in an H2-rich background atmosphere. If the planet is a hycean world (liquid water ocean + hydrogen-dominated atmosphere), it could be habitable under certain conditions. The presence of carbon, hydrogen and oxygen was already confirmed, however, there was no detection of nitrogen or its compounds. Molecular nitrogen is difficult to detect directly. This study concentrates on possible photochemical products of N2 such as HCN, NH3 and HC3N. We set approximate limits on the amount of nitrogen bearing species by varying atmospheric parameters, such as the Eddy Diffusion coefficient and the amount of N2 present from 10 ppm to 10%. If the bulk nitrogen-containing gas in the atmosphere is N2, photochemistry produces only trace amounts of the aforementioned species. However, if ammonia is the main source of nitrogen, then the quantities of NH3, CH5N and HCN approach detectable range. HC3N and NO are bad tracers of the nitrogen source in the atmosphere, because they are produced in similar amounts in all tested scenarios. Assuming equilibrium chemistry
The internal structures of Uranus and Neptune remain unknown. In addition, sub-Neptunes are now thought to be the most common type of exoplanets. Understanding the physical processes that govern the interiors of such planets is therefore essential. Phase separation between hydrogen and water may occur in cold, water-rich intermediate-mass planets. We assess whether it could occur in Uranus, Neptune, K2-18\,b and TOI-270\,d, and investigate its effect on the planetary evolution and inferred internal structure. We couple planetary evolution models with recent \textit{ab initio} calculations of the hydrogen-water phase diagram, allowing for temperature shifts to account for uncertainties in miscibility gaps. We find that demixing may occur and could lead to a complete depletion of water in the outermost regions of Uranus and Neptune. Temperature offsets of up to 1100~K lead to a depleted region comprising as much as 16\% of the planet's mass, and an increase in planetary radius by nearly 20\%. For K2-18\,b, our models suggest that hydrogen-water demixing is ongoing and may explain the absence of water features in its JWST spectrum. A temperature offset of 500~K is required to get a co
We present an in-depth, high-resolution spectroscopic analysis of the M dwarf K2-18 that hosts a sub-Neptune exoplanet in its habitable zone. We show our technique to accurately normalize the observed spectrum, which is crucial for a proper spectral fitting. We also introduce a new automatic, line-by-line model-fitting code, AutoSpecFit, that performs an iterative $χ^{2}$ minimization process to measure individual elemental abundances of cool dwarfs. We apply this code to the star K2-18, and measure the abundance of 10 elements - C, O, Na, Mg, Al, K, Ca, Sc, Ti, and Fe. We find these abundances moderately supersolar, except for Fe with a slightly subsolar abundance. The accuracy of the inferred abundances is limited by the systematic errors due to uncertain stellar parameters. We also derive the abundance ratios associated with several planet-building elements such as Al/Mg, Ca/Mg, Fe/Mg, and (a solar-like) C/O=0.568 $\pm$ 0.026, which can be used to constrain the chemical composition and the formation location of the exoplanet. On the other hand, the planet K2-18 b has attracted considerable interest, given the JWST measurements of its atmospheric composition. Early JWST studies r
Results from the Kepler mission indicate that the occurrence rate of small planets ($<3$ $R_\oplus$) in the habitable zone of nearby low-mass stars may be as high as 80%. Despite this abundance, probing the conditions and atmospheric properties on any habitable-zone planet is extremely difficult and has remained elusive to date. Here, we report the detection of water vapor and the likely presence of liquid and icy water clouds in the atmosphere of the $2.6$ $R_\oplus$ habitable-zone planet K2-18b. The simultaneous detection of water vapor and clouds in the mid-atmosphere of K2-18b is particularly intriguing because K2-18b receives virtually the same amount of total insolation from its host star ($1368_{-107}^{+114}$ W m$^{-2}$) as the Earth receives from the Sun (1361 W m$^{-2}$), resulting in the right conditions for water vapor to condense and explain the detected clouds. In this study, we observed nine transits of K2-18b using HST/WFC3 in order to achieve the necessary sensitivity to detect the water vapor, and we supplement this data set with Spitzer and K2 observations to obtain a broader wavelength coverage. While the thick hydrogen-dominated envelope we detect on K2-18b m
The organosulfur biosignature gases dimethylsulfide (DMS) and dimethlydisulfide (DMDS) have recently been claimed to be present in the atmosphere of sub-Neptune exoplanet K2-18b, leading to the suggestion of possible extraterrestrial life. Abiotic formation pathways for DMS and DMDS in reducing atmospheres have also been proposed, raising concern over the use of DMS and DMDS as biosignature gases more generally. In this paper we independently test and contrast the proposed abiotic formation pathways for DMS and DMDS using K2-18b as a case study, and explore the wider implications for the atmospheric carbon and sulfur chemistry of hydrogen-rich sub-Neptunes. We demonstrate that one proposed formation pathway is capable of producing observable abundances of abiotic DMS and DMDS, however it depends sensitively on the energy barrier of the limiting step, which remains unmeasured experimentally. The formation of hydrocarbons including C2H6, however, occurs abundantly and offers a plausible alternative explanation to the reported suggestions of organosulfur compounds on K2-18b, having previously been shown to share similar spectral features with DMS and DMDS at near-IR wavelengths. Final
Energy limits that delineate the `habitable zone' for exoplanets depend on a given exoplanet's net planetary albedo (or `Bond albedo'). We here demonstrate that the planetary albedo of an observed exoplanet is limited by the above-cloud atmosphere - the region of the atmosphere that is probed in remote observation. We derive an analytic model to explore how the maximum planetary albedo depends on the above-cloud optical depth and scattering versus absorbing properties, even in the limit of a perfectly reflective grey cloud layer. We apply this framework to sub-Neptune K2-18b, for which a high planetary albedo has recently been invoked to argue for the possibility of maintaining a liquid water ocean surface, despite K2-18b receiving an energy flux from its host star that places it inside of its estimated `habitable zone' inner edge. We use a numerical multiple-scattering line-by-line radiative transfer model to retrieve the albedo of K2-18b based on the observational constraints from the above-cloud atmosphere. Our results demonstrate that K2-18b's observed transmission spectrum already restricts its possible planetary albedo to values below the threshold required to be potentially
Recent JWST detections of CH4 and CO2 in sub-Neptune atmospheres point to a link between atmospheric composition and the nature of planetary building blocks - rock, water, or refractory carbon ("soot") - yet this connection remains poorly understood. Here we investigate how different formation environments shape the coupled interior and atmospheric compositions of sub-Neptunes. We model planets assembled from varying proportions of rock, water, and soot and compute the global chemical equilibrium and the overlying atmospheric structure. We find that planets formed from water-poor material produce atmospheres strongly depleted in carbon-bearing species, with log(CH4) and log(CO2) below -4. In contrast, planets assembled from water-rich building blocks naturally develop methane- and carbon-dioxide-rich atmospheres with elevated metal mass fractions and C/O ratios. The presence of refractory carbon (soot) further enhances methane production and can lead to methane-dominated atmospheres. Comparison with JWST observations suggests that water-rich formation is sufficient to explain K2-18b and TOI-270d with no soot component required, while TOI-421b and GJ3470b are consistent with water-p
Recent transit observations of K2-18b and TOI-270d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (T$_\mathrm{eq}$=250-400K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO$_2$ abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here, we present the JWST NIRSpec/PRISM 0.7-5.4$\mathbfμ$m transmission spectrum of a third temperate sub-Neptune, the 2.4R$_\oplus$ planet LP 791-18c (T$_\mathrm{eq}$=355K), which is even more favorable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite LP 791-18c's radius, mass, and equilibrium temperature being in between those of K2-18b and TOI-270d, we find a drastically different transmission spectrum. While we also detect methane on LP 791-18c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO$_2$ absorption. Overall, we infer a deep metal-enriched atmosphere (246-415$\times$solar) for LP 791-18c, with a CO$_2$-to-CH$_4$ ratio small