With the advancement of nanoscience, silver/silver chloride (Ag/AgCl) electrodes have become widely utilised in microscale and nanoscale fluidic experiments, because of their stability. However, our findings reveal that the dissolution of AgCl from the electrode in \ch{Cl-}-rich solutions can lead to significant silver contamination, through the formation of silver complexes, \ch{[AgCl_{n+1}]^{n-}}. We demonstrate the electrodeposition of silver particles on graphene in KCl aqueous solution, with AgCl dissolution from the electrode as the sole source of silver. This unexpected electrodeposition process offers a more plausible interpretation of the recently reported ``ionic flow-induced current in graphene''. That is, the measured electronic current in graphene is due to the electrodeposition of silver, challenging the previously claimed ``ionic Coulomb drag''. More caution is called for when using Ag/AgCl electrodes in microfluidic, and especially nanofluidic systems, because AgCl dissolution should not be neglected.
Quantum decoherence is both the fundamental mechanism underlying the quantum-to-classical transition and a major challenge for the development of scalable nanoscale quantum technologies. This work introduces a Quantum Phase Space (QPS) framework that provides a unified geometric description of decoherence. The framework is based on a dual structure consisting of an overcomplete continuous frame of minimum-uncertainty states that defines the QPS geometry, and an orthonormal basis that satisfies the strict mathematical requirements for decoherence within the Spectrum Broadcast Structure (SBS) objectivity criterion for pointer states. Within this framework, the variance-covariance matrix of the QPS ground states serves as a universal indicator of decoherence regimes:it is time-independent for Markovian (memoryless) dynamics, and time-dependent for non-Markovian dynamics with memory and information backflow. To illustrate the formalism, the Hu-Paz-Zhang (HPZ) model is generalized to include simultaneous position and momentum couplings to the environment, leading to a generalized non-Markovian master equation characterized by a spectral-density matrix. The corresponding evolution equati
Fundamental issues of 1/f noise in quantum nanoscience are reviewed starting from basic statistical noise processes. Fundamental noise models based on two-level systems (TLS) are described. We emphasize the importance of TLSs in materials parameter fluctuations, such as dielectric constant. The present understanding of 1/f noise in superconducting quantum interferometers and in single electron devices is summarized. For coherent quantum nanoscience, we introduce superconducting qubits and the relation between decoherence and 1/f noise using the filter function formulation. We also clarify the qubit noise spectroscopy and emphasize the importance of materials with reduced 1/f noise for future quantum coherent nanodevices.
For the past three decades, nanoscience has widely affected many areas in physics, chemistry, and engineering, and has led to numerous fundamental discoveries as well as applications and products. Concurrently, quantum science and technology has developed into a cross-disciplinary research endeavour connecting these same areas and holds a burgeoning commercial promise. Although quantum physics dictates the behaviour of nanoscale objects, quantum coherence, which is central to quantum information, communication and sensing has not played an explicit role in much of nanoscience. This Review describes fundamental principles and practical applications of quantum coherence in nanoscale systems, a research area we call quantum-coherent nanoscience. We structure this manuscript according to specific degrees of freedom that can be quantum-coherently controlled in a given nanoscale system such as charge, spin, mechanical motion, and photons. We review the current state of the art and focus on outstanding challenges and opportunities unlocked by the merging of nanoscience and coherent quantum operations.
This paper describes some of the results of a National Science Foundation Nanotechnology Undergraduate Education project that aims to establish a nanoscience and nanotechnology program at the University of North Dakota. The goal is to generate new interest in nanoscience and nanotechnology among engineering and science students and prepare them with the knowledge and skills necessary for the next generation of graduates to compete in the global market and contribute to the nanoscience and nanotechnology field. The project explored several aspects of student learning, including students motivations for investigating nanotechnology through interdisciplinary coursework. To collect this information, a survey was administered to students who enrolled to two nanoscience and nanotechnology courses. Data collected from the survey will be used to improve the design and delivery of future courses as part of constructing a complete nanoscience and nanotechnology curriculum.
SALMON (Scalable Ab-initio Light-Matter simulator for Optics and Nanoscience, http://salmon-tddft.jp) is a software package for the simulation of electron dynamics and optical properties of molecules, nanostructures, and crystalline solids based on first-principles time-dependent density functional theory. The core part of the software is the real-time, real-space calculation of the electron dynamics induced in molecules and solids by an external electric field solving the time-dependent Kohn-Sham equation. Using a weak instantaneous perturbing field, linear response properties such as polarizabilities and photoabsorptions in isolated systems and dielectric functions in periodic systems are determined. Using an optical laser pulse, the ultrafast electronic response that may be highly nonlinear in the field strength is investigated in time domain. The propagation of the laser pulse in bulk solids and thin films can also be included in the simulation via coupling the electron dynamics in many microscopic unit cells using Maxwell's equations describing the time evolution of the electromagnetic fields. The code is efficiently parallelized so that it may describe the electron dynamics i
Isotopetronics is a new branch of the nanoscience. This paper is briefly reviwed the main parts of isotopetronics.
The production, observation and manipulation of very small objects is a tour de force, but these objects, which could infiltrate anywhere without being seen, may arouse suspicion. To assess the situation at best, we describe the activity of a nanoscience research institution, some of the methods used there, the spirit of its researchers and their attitude towards risk.
Proper field delineation plays an important role in scientometric studies, although it is a tough task. Based on an emerging and interdisciplinary field, nanoscience and nanotechnology, this paper highlights the problem of field delineation. First, we review the related literature. Then, three different approaches to delineate a field of knowledge were applied at three different levels of aggregation: subject category, publication level, and journal level. Expert opinion interviews served to assess the data, and precision and recall of each approach were calculated for comparison. Our findings confirm that field delineation is a complicated issue at both the quantitative and the qualitative level, even when experts validate results.
One is inclined to conceptualize impact in terms of citations per publication, and thus as an average. However, citation distributions are skewed, and the average has the disadvantage that the number of publications is used in the denominator. Using hundred percentiles, one can integrate the normalized citation curve and develop an indicator that can be compared across document sets because percentile ranks are defined at the article level. I apply this indicator to the set of 58 journals in the ISI Subject Category of "Nanoscience & nanotechnology," and rank journals, countries, cities, and institutes using non-parametric statistics. The significance levels of results can thus be indicated. The results are first compared with the ISI-Impact Factors, but this Integrated Impact Indicator (I3) can be used with any set downloaded from the (Social) Science Citation Index. The software is made publicly available at the Internet. Visualization techniques are also specified for evaluation by positioning institutes on Google Map overlays.
Single atom/molecule manipulation with a scanning-tunneling-microscope (STM) tip is an innovative experimental technique of nanoscience. Using STM-tip as an engineering or analytical tool, artificial atomic-scale structures can be fabricated, novel quantum phenomena can be probed, and properties of single atoms and molecules can be studied at an atomic level. In thi sarticle, various STM manipulation procedures are described.
The journal set which provides a representation of nanoscience and nanotechnology at the interfaces among applied physics, chemistry, and the life sciences is developing rapidly because of the introduction of new journals. The relevant contributions of nations can be expected to change according to the representations of the relevant interfaces among journal sets. In the 2005 set the position of the USA decreased more than in the 2004-set, while the EU-27 gained in terms of its percentage of world share of citations. The tag "Y01N" which was newly added to the EU classification system for patents, allows for the visualization of national profiles of nanotechnology in terms of relevant patents and patent classes.
This article examines the cognitive evolution and disciplinary diversity of nanotechnology as expressed through the terminology used in titles of nano journal articles. The analysis is based on the NanoBank bibliographic database of 287,106 nano articles published between 1981 and 2004. We perform multifaceted analyses of title words, focusing on 100 most frequent terms. Hierarchical clustering of title terms reveals three distinct time periods of cognitive development of nano research: formative (1981-1990), early (1991-1998), and current (after 1998). Early period is characterized by the introduction of thin film deposition techniques, while the current period is characterized by the increased focus on carbon nanotube and nanoparticle research. We introduce a method to identify disciplinary components of nanotechnology. It shows that the nano research is being carried out in a number of diverse parent disciplines. Currently only 5% of articles are published in dedicated nano-only journals. We find that some 85% of nano research today is multidisciplinary. Hierarchical clustering of disciplinary components reveals that the cognitive content of current nanoscience can be divided in
The emergence of districts in nanotechnology represents a new pattern of scientific development. The factors affecting their growth are analysed to understand the drivers of economic development. By analyzing the top 200 nano-districts, Nanotrendchart sheds light on the clusterization process: academic production is seen to be highly concentrated, with fifteen districts representing over half of published articles; Asian districts are clearly growing significantly faster than those elsewhere; and district growth in the domain of engineering and physics is more rapid than in other disciplines. Scientific diversity, actors diversity as well as the degree of openness of the cluster influence their evolution. Highly specialised clusters witness lower growth rates
The second order (in time) Schrodinger equation is proposed. The additional term (in comparison to Schrodinger equation) describes the interaction of particles with vacuum filled with virtual particle-antiparticle pairs (zitterbewegung). Key words: Schrodinger equation; Nanoscience; Zitterbewegung.
We present an overview of recent progress in plasmonics. We focus our study on the observation and excitation of surface plasmon polaritons (SPPs) with optical near-field microscopy. We discuss in particular recent applications of photon scanning tunnelling microscope (PSTM) for imaging of SPP propagating in metal and dielectric wave guides. We show how near-field scanning optical microscopy (NSOM) can be used to optically and actively address remotely nano-objects such as quantum dots. Additionally we compare results obtained with near-field microscopy to those obtained with other optical far-field methods of analysis such as leakage radiation microscopy (LRM).
Superconductivity can be modified by various effects related to randomness, disorder, structural defects, and other similar physical effects. Their affects on superconductivity are important because such effects are intrinsic to certain material system's preparation, or may be intentionally produced. In this work we show in the context of a Cooper instability relationship, that introduction of disorder through impurities could possibly lead to an increase in critical temperature. This is an old subject, having been addressed decades ago in the view of simpler substances, including metal alloy materials. Today, with the advances in material science, nanoscience, and atomic level preparation of materials and devices, this subject should be reexamined. That is our purpose here, especially in light of some recent discoveries made in the area of the metal-insulator transition, to be covered herein. One may obtain a formula for the critical temperature which is recognizable, and relatable to Bardeen-Cooper-Schrieffer theory, by using many-body quantum theory for condensed matter expeditiously, using quantum Green's functions, polarization functions (correlation functions), and vertex fun
In this paper the interaction of attosecond laser pulses with matter is investigated. The scattering and potential motion of heat carriers as well as the external force are considered. Depending on the ratio of the scatterings and potential motion the heat transport is described by the thermal forced Klein-Gordon or thermal modified telegraph equation. For thermal Heisenberg type relation V tau=hbar (tau is the relaxation time and V is the potential) the heat transport is described by the thermal distortionless damped wave equation. In this paper Klein-Gordon modified telegraph equation and wave equation are solved. Key words: Attosecond laser pulses; Quantum heat transport equation; Klein-Gordon thermal equation.
The evolution of cluster structure with size and the critical size for the transition from cluster to nanocrystal have long been fundamental problems in nanoscience. Due to limitations of experimental technology and computational methods, the exploration of the continuous evolution of clusters towards nanocrystal is still a big challenge. Here, we proposed a machine learning force field (MLFF) that can generalize well to various copper systems ranging from small clusters to large clusters and bulk. The continuous evolution of copper clusters CuN towards nanocrystal was revealed by investigating clusters in a wide size range (7 <= N <= 17885) based on MLFF simulated annealing. For small CuN (N < 40), electron counting rule plays a major role in stability. For large CuN (N > 80), geometric magic number rule plays a dominant role and the evolution of clusters is based on the formation of more and more icosahedral shells. For medium size CuN (40 <= N <= 80), both rules contribute. The critical size from cluster to nanocrystal was calculated to be around 8000 atoms (about 6 nm in diameter). Our work terminates the long-term challenge in nanoscience, and lay the methodo
Nanoscience at times can seem out of reach to the developing world and the general public, with much of the equipment expensive and knowledge seemingly esoteric to nonexperts. Using only cheap, everyday household items, accessible research with real applications can be shown. Here, graphene suspensions were produced using pencil lead, tap water, kitchen appliances, soaps and coffee filters, with a childrens glue based graphene nanocomposite for highly sensitive pulse measurements demonstrated.