Herein, we report a minireview to give a brief introduction of applications of nanomaterials in the field of forensic science. The materials that have their size in nanoscale (1 - 100 nm) comes under the category of nanomaterials. Nanomaterials possess various applications in different fields like cosmetic production, medical, photoconductivity etc. because of their physio-chemical, electrical and magnetic properties. Due to the different characteristic property that nanomaterials have, they are widely employed in diverse domains. In various fields of forensic science such as fingerprints, toxicology, medicine, serology, nanomaterials are being used extensively. Large surface area to volume ratio of the materials in nano-regime makes the nanomaterials suitable for all these application with high efficiency. This review article briefs about the nanomaterials, their advantages and their novel applications in various fields, focusing especially in the field of forensic science. The basic idea of different areas of forensic science such as development of fingerprints, detection of drugs, estimating the time since death, analysis of GSR, detection of various explosives and for the extra
Biocompatibility is a critical factor in the application of nanomaterials in medical fields, as these materials must interact safely and effectively with biological systems to be viable for therapeutic and diagnostic use. This article investigates the biocompatibility of nanomaterials, focusing on their interactions with biological cells, tissues, and the immune system. Key properties such as surface chemistry, size, shape, and material composition are examined, as they significantly influence the biological response. The article explores the role of nanomaterials in medical applications, including drug delivery, diagnostic imaging, and tissue engineering, while discussing the challenges involved in enhancing their biocompatibility. A case study on the CaO-CaP binary system is presented, showcasing the use of calcium oxide (CaO) and calcium phosphate (CaP) nanoparticles in bone tissue engineering. This system is widely investigated for its ability to mimic the mineral content of bone and promote osteogenesis, highlighting both its therapeutic potential and challenges in ensuring safe biocompatibility in clinical settings. The article concludes by reviewing strategies to optimize th
Quantification of nonlinear optical properties is required for nano-optical devices, but they are challenging to measure on a nanomaterial. Here, we harness enhanced optical fields inside a plasmonic nanocavity to mediate efficient nonlinear interactions with the nanomaterials. We performed reflection Z-scan technique at intensity levels of kWcm^2, reaching down to two photons per pulse, in contrast to GWcm^2 in conventional methods. The few photons are sufficient to extract the nonlinear refractive index and nonlinear absorption coefficient of different nanomaterials, including perovskite and Au nano-objects and a molecular monolayer. This work is of great interest for investigating nonlinear optical interactions on the nanoscale and characterizing nanomaterials, including fragile biomolecules.
The rapid development in nanotechnology has necessitated accurate and efficient assembly strategies for nanomaterials. Monolayer assembly of nanomaterials (MAN) represents an extreme challenge in manufacturing and is critical in understanding interactions among nanomaterials, solvents, and substrates. MAN enables highly tunable performance in electronic and photonic devices. This review summarizes the recent progress on the methods to achieve MAN and discusses important control factors. Moreover, the importance of MAN is elaborated by a broad range of applications in electronics and photonics. In the end, we outlook the opportunities as well as challenges in manufacturing and new applications.
The outstanding multidisciplinary applicability of nanomaterials has paved the path for the rapid advancement of nanoscience during the last few decades. Such technological progress subsequently results in an inevitable environmental exposure of nanomaterials. Presently, nanomaterials are employed in an extensive range of commercial products. Safe and sustainable incorporation of nanomaterials in industrial products requires a profound and comprehensive understanding of their potential toxicity. Among different nanomaterials, carbon nanomaterials marked its notable superiority toward the development of state-of-the-art nanotechnology due to the significant contribution of each of the carbon allotropes with varied dimensionality. The zero-dimensional fullerene, one-dimensional carbon nanotube, and two-dimensional graphene possess an exclusive combination of distinctive properties that are utilized in most of the nanotechnology-based products nowadays. However, potential risk factors are associated with the production and the use of carbon nanomaterials. Consequently, the number of studies regarding the assessment of the toxicity of these nanomaterials has increased rapidly in the pa
The study of van der Waals (vdW) materials has seen increased interest in recent years, due to the wide range of uses for these materials because of their unique mechanical, electronic, and optical properties. This area has recently expanded further into studying the behavior of vdW nanomaterials, as decreasing dimensions open up opportunities to interact with these materials in new ways. However, measuring the band structures of nanomaterials, which is key to understanding how confinement affects material properties and interactions, comes with several challenges. In this review, we survey a range of techniques for synthesizing and characterizing vdW nanomaterials, in order to outline the key material and characterization challenges. This includes controlling the Fermi level in vdW nanoparticles, preparing these particles for either ensemble or individual particle measurement, as well as protecting the pristine surface from oxidation.
Intensive concerns about the biosafety of nanomaterials demand the systematic study of the mechanisms about their biological effects. Many biological effects can be attributed to the interaction of nanomaterials with protein and their impacts on protein function. On the other hand, nanomaterials exhibit the potential in a variety of biomedical applications, many of which also involve the direct interaction with protein. In this paper, we review some recent computational studies about this subject, especially the interaction of carbon and gold nanomaterials. Besides the hydrophobic and π-stacking interactions, the interaction mode of carbon nanomaterials can be regulated by their functional groups. And the coating of gold nanomaterials also adjusts their interaction mode, in addition to the coordination interaction with cysteine's sulfur group and histidine's imidazole group. Moreover, nanomaterials can interact with multiple proteins and the impacts on protein activity are attributed to a wide spectrum of mechanisms. The findings about the mechanisms of nanomaterial-protein interaction can further guide the design and development of nanomaterial to realize the applications in disea
Multiphoton absorption (MPA) is a nonlinear optical process that involves simultaneous absorption of two or more photons by a material to promote its ground state to an excited state. Multiphoton absorption promises many important applications such as multi-dimensional fluorescence imaging, three dimensional (3D) data storage. Physical and chemical properties of nanometer sized semiconductor materials change drastically due to quantum size effect. Combination of both multiphoton absorption and quantum effects will be an interesting study. Multiphoton absorption of semiconducting nanomaterials is an exciting phenomenon which promotes many important applications. This paper reviews multi-photon absorption properties of different kinds of semiconducting nanomaterials starting from chalcogenide-based nanomaterials to perovskites nanomaterials and their applications in various fields.
The development of science-based categorization strategies for regulatory purposes is not a simple task. It requires understanding the needs and capacity of a wide variety of stakeholders and should consider the potential risks and unintended consequences. For an evolving science area, such as nanotechnologies, the overall uncertainties of designing an effective categorization scheme can be significant. Future nanomaterials may be far more complex and may integrate far different functionalities than modern nanomaterials. There is much that has been learned from our experience with legacy nanomaterials and particulate substances in general. Most of the modern nanomaterials are not new nor dramatically different from parent or existing chemical substances, however there are some nuances. Applying these learnings to define reasonable science-based categories that consider how different emerging nanomaterials might be from existing known substances (while integrating sound concepts as they develop) would be a pragmatic and flexible path forward. However, there are many barriers down this road including a need for improvement and updates to chemical classification systems to improve haz
Auxetic materials (materials with negative Poisson's ratio) and nanomaterials have independently been for many years two of the most active research fields in material science. Recently, these formerly independent fields have begun to intersect in new and interesting ways due to the recent discovery of auxeticity in nanomaterials like graphene, metal nanoplates, black phosphorus, and others. Here we review the research emerging at the intersection of auxeticity and nanomaterials. We first survey the atomistic mechanisms, both intrinsic and extrinsic, that have been found, primarily through atomistic simulations, to cause auxeticity in nanomaterials. We then outline the available experimental evidence for auxetic nanomaterials. In order to lay the groundwork for future work in this exciting area, we close by discussing several future prospects as well as the current challenges in this field.
Quantum information science and engineering (QISE) which entails use of quantum mechanical states for information processing, communications, and sensing and the area of nanoscience and nanotechnology have dominated condensed matter physics and materials science research in the 21st century. Solid state devices for QISE have, to this point, predominantly been designed with bulk materials as their constituents. In this review, we consider how nanomaterials (i.e. materials with intrinsic quantum confinement) may offer inherent advantages over conventional materials for QISE. We identify the materials challenges for specific types of qubits, and we identify how emerging nanomaterials may overcome these challenges. Challenges for and progress towards nanomaterials based quantum devices are identified. We aim to help close the gap between the nanotechnology and quantum information communities and inspire research that will lead to next generation quantum devices for scalable and practical quantum applications.
The integration of biosensing platforms with drug delivery systems has led to effective treatment strategies for biomedical applications. With the emergency of nanotechnology, the manipulation of materials in the nanometer, these biosensing and drug delivery systems have been tremendously improved due to the exceptional properties exhibited by these materials. The conventional approaches used to synthesize the nanomaterials including physical and chemical methods involve the usage of harsh chemicals and hazardous reaction conditions and hence posing a threat to health and the environment. This problem is solved by the biological methods that involve green nanotechnology which integrates green chemistry and engineering principles to formulate harmless and eco-friendly nanomaterials to fight the complications affecting human health and the environment. These biological methods use phytochemicals found in plants and plants parts as well as microorganisms for the bioreduction of metal ions to their corresponding nanomaterials. The plants and the microorganisms are readily available, cost-efficient, and have biocompatibility hence offering sustainable synthetic methods for nanomaterials
The rapid outbreaks of lethal viruses necessitate the development of novel antiviral substance. Besides the conventional antiviral substances, biocompatible nanomaterials also have significant potential in combating the virus at various stages of infection. Carbon nanomaterials have an impressive record against viruses and can deal with many crucial healthcare issues. In accordance with the published literature, biocompatible carbon nanomaterials have a promising prospect as an antiviral substance. Subsequently, the antiviral properties of different carbon nanomaterials namely fullerene, carbon nanotube, carbon dot and graphene oxide have been reviewed.
This review summarizes the current studies of the thermal transport properties of one-dimensional (1D) carbon nanomaterials and nanoarchitectures. Considering different hybridization states of carbon, emphases are laid on a variety of 1D carbon nanomaterials, such as diamond nanothreads, penta-graphene nanotubes, supernanotubes, and carbyne. Based on experimental measurements and simulation/calculation results, we discuss the dependence of the thermal conductivity of these 1D carbon nanomaterials on a wide range of factors, including the size effect, temperature influence, strain effect, and others. This review provides an overall understanding of the thermal transport properties of 1D carbon nanomaterials and nanoarchitectures, which paves the way for effective thermal management at nanoscale.
In the last three decades, zero-dimensional, one-dimensional, and two-dimensional carbon nanomaterials (i.e., fullerenes, carbon nanotubes, and graphene, respectively) have attracted significant attention from the scientific community due to their unique electronic, optical, thermal, mechanical, and chemical properties. While early work showed that these properties could enable high performance in selected applications, issues surrounding structural inhomogeneity and imprecise assembly have impeded robust and reliable implementation of carbon nanomaterials in widespread technologies. However, with recent advances in synthesis, sorting, and assembly techniques, carbon nanomaterials are experiencing renewed interest as the basis of numerous scalable technologies. Here, we present an extensive review of carbon nanomaterials in electronic, optoelectronic, photovoltaic, and sensing devices with a particular focus on the latest examples based on the highest purity samples. Specific attention is devoted to each class of carbon nanomaterial, thereby allowing comparative analysis of the suitability of fullerenes, carbon nanotubes, and graphene for each application area. In this manner, this
Solid state impedance spectroscopy enables the various contributions to the resistive and capacitive properties of electronically inhomogeneous condensed matter to be deconvoluted and characterized separately. The different contributions arise from electronically distinct areas in the sample, which can in an ideal case be represented each by one standard RC element. In the following, the basic principles of impedance spectroscopy, different types of experimental setups and several examples of experimental impedance data sets from nanostructured materials are reviewed and discussed. The data analysis and equivalent circuit modelling processes which are relevant for the application of this technique to nanomaterials are emphasized. The different dimensions and structure of nanomaterials as compared to macroscopic bulk samples leads to quite different and sometimes more complex data that require detailed analysis and advanced equivalent circuit models.
Categorization approaches have been effectively applied to chemicals, and many have tried to apply variations of these approaches to nanomaterials. Given the added complexities of nanomaterials, this has been challenging. International cooperation on categorization approaches has been made, primarily through the Organization for Economic Cooperation and Development. Progress has been limited given the complexities of nanomaterials, especially given the need to consider not only the intrinsic properties of the materials but also properties dependent on the system into which it is introduced. Consideration must also be given to the different purposes and contexts, in particular regulatory contexts, to which the categorization schemes would be applied. More progress can be anticipated by focusing on areas of overlap among countries such as physicochemical properties.
High-entropy nanomaterials have been arousing considerable interest in recent years due to their huge composition space, unique microstructure, and adjustable properties. Previous studies focused mainly on high-entropy nanoparticles, while other high-entropy nanomaterials were rarely reported. Herein, we reported a new class of high-entropy nanomaterials, namely (Ta0.2Nb0.2Ti0.2W02Mo0.2)B2 high-entropy diboride (HEB-1) nanoflowers, for the first time. The formation possibility of HEB-1 was first theoretically analyzed from two aspects of lattice size difference and chemical reaction thermodynamics. We then successfully synthesized HEB-1 nanoflowers by a facile molten salt synthesis method at 1473 K. The as-synthesized HEB-1 nanoflowers showed an interesting chrysanthemum-like morphology assembled from numerous well-aligned nanorods with the diameters of 20-30 nm and lengths of 100-200 nm. Meanwhile, these nanorods possessed a single-crystalline hexagonal structure of metal diborides and highly compositional uniformity from nanoscale to microscale. In addition, the formation of the as-synthesized HEB-1 nanoflowers could be well interpreted by a classical surface-controlled crystal g
Modern nanomaterials contain complexity that spans all three dimensions - from multigate semiconductors to clean energy nanocatalysts to complex block copolymers. For nanoscale characterization, it has been a long-standing goal to observe and quantify the three-dimensional (3D) structure - not just surfaces, but the entire internal volume and the chemical arrangement. Electron tomography estimates the complete 3D structure of nanomaterials from a series of two-dimensional projections taken across many viewing angles. Since its first introduction in 1968, electron tomography has progressed substantially in resolution, dose, and chemical sensitivity. In particular, scanning transmission electron microscope tomography has greatly enhanced the study of 3D nanomaterials by providing quantifiable internal morphology and spectroscopic detection of elements. Combined with recent innovations in computational reconstruction algorithms and 3D visualization tools, scientists can interactively dissect volumetric representations and extract meaningful statistics of specimens. This article highlights the maturing field of electron tomography and the widening scientific applications that utilize 3
In this article we explore the analytical and policy implications of widening the governance of nanomaterials from the focus on risk regulation to a broader focus on the governance of innovation. To do this, we have analysed the impact of industrial activities on nanotechnology governance, while previous studies have concentrated on risk appraisal, public perceptions, public engagement, regulatory frameworks and related policies. We argue that the specific characteristics of the industrial dynamics of nanomaterials - flexibility in applications and distributed innovation - have important implications for innovation governance as they limit and enable different interventions to attempt to shape technology. Flexibility and distributedness exacerbate the difficulties of directly controlling or shaping the directions of nanomaterials innovation. In particular, the potential for public policy leverage is hindered by the bottom-up nature of governance resulting from the multiplicity of innovation sites. Under these conditions, we argue that the framing of policies for nanomaterials governance needs to be broadened. The prevailing emphasis on policy initiatives upstream, while commendable