Understanding the fundamental limits of state convertibility is crucial for establishing the boundaries of quantum information processing and thermodynamic efficiency. While auxiliary systems, catalysts, can facilitate otherwise impossible transformations, standard catalysis rigidly requires the auxiliary system to return to its exact initial state. In this work, we investigate the power of flexible catalysis, where the catalyst evolves through a cycle of states, restoring its initial configuration only after a finite number of steps. Focusing on the regime of fixed, finite dimensions, we analyze the capabilities of flexible catalysis within the resource theories of entanglement and quantum thermodynamics. In the context of entanglement, we derive conditions limiting flexible catalysts, yet show that flexible catalysis can be strictly more powerful than same-dimensional standard catalysis: it enables deterministic transformations achievable by no standard catalyst of the same dimension, and it strictly increases the success probability of stochastic local operations and classical communication. A similar deterministic advantage arises in quantum thermodynamics, where flexible catal
We present a new approach to identify satellite trails (or other linear artifacts) in ACS/WFC imaging data using a modified Radon Transform. We demonstrate that this approach is sensitive to features with mean brightness significantly below the background noise level, and it is resistant to the influence of bright astronomical sources (e.g., stars, galaxies) in most cases. Comparing with a set of satellite trails identified by eye, we find a trail recovery rate of 85\% and a false detection rate (after removing diffraction spikes that are easily filtered) of 2.5\%. By performing an analysis using a much larger ACS/WFC data set where false trails are identified by their persistence across multiple images of the same field, we identify the Radon Transform parameter space and image properties where our algorithm is unreliable, and estimate a false detection rate of $\sim10\%$ elsewhere. We apply our method to ACS/WFC data taken between 2002 and 2022 to determine both the frequency of satellite trail contamination in science data and also the typical trail brightness as a function of time. We find the rate of satellite trail contamination has increased by approximately a factor of two
The noise in bias frames for all four readout amplifiers in the Advanced Camera for Surveys (ACS) Wide Field Channel (WFC) is dependent on row number. This is because dark current accumulated during readout increases across the detector, influencing and increasing the read noise as a function of row number. In this report, we investigate bias frames taken with the ACS/WFC to explore the column dependence of read noise for each of the amplifiers for different anneal periods. Analyzing the data, we find that there is no column dependence of read noise and that the read noise values for the physical pre-scans are approximately 0.5 e$^-$ lower than in the science arrays because there is no readout dark accumulated in this area. We further investigate 1) the evolution of read noise over an anneal period, 2) a linear decrease in read noise within the initial columns per amplifier, and 3) pixels in elevated read noise columns. We conclude that 1) there is no visual trend of read noise over an anneal period, 2) amplifiers A and C have an initial linear decrease of read noise in the science arrays, and 3) masking unstable hot pixels in a column will decrease its read noise values.
Using repeat imaging of a galaxy cluster taken over a seventeen-year baseline, we examine the impact that degraded Charge Transfer Efficiency (CTE) has on photometric measurements of extended sources using the ACS/WFC on HST. We examine how measured brightnesses depend on time since ACS installation, source location on the WFC detectors, source brightness, and local background level in individual exposures. We find that global brightness measurements using large apertures are generally reliable within $\sim$0.05 magnitudes across the WFC detectors if exposure backgrounds are above $20e^-/{pixel}$ and sources are brighter than $\sim300e^-$ in a single exposure. However, brightness measurements on smaller scales can suffer deficiencies in excess of 0.1 mags (sometimes, significantly more) in recent data unless sources are very close to the CCD serial registers ($\lesssim 512$ pixels), or brighter than $\sim3000\,e^-$ in a single exposure. We also show how degraded CTE can result in artificial asymmetries in galaxy light distributions, which are largely mitigated if backgrounds are $>20e^-/{pixel}$ and targets are not far ($>1536$ pixels) from the serial registers. As expected,
In 2024, due to some operational changes, the Hubble Space Telescope began exhibiting undeclared loss of lock events. This loss of lock can result in the smearing out of light from the target field during an exposure, which leads to data degradation, which in turn may require data to be retaken. In this work, we investigate this `roll-drift' effect in ACS/WFC images. We quantify the impact of roll-drift on measurable parameters in data by using simulations and existing data reduction techniques. We identify a threshold of one such measurable parameter beyond which data may likely be affected by roll-drift, so that users can quickly and easily assess whether their data needs further attention.
We have used 23 years of Hubble Space Telescope ACS/SBC data to study what background levels are encountered in practice and how much they vary. The backgrounds vary considerably, with F115LP, F122M, F125LP, PR110L, and PR130L all showing over an order of magnitude of variation in background between observations, apparently due to changes in airglow. The F150LP and F165LP filters, which are dominated by dark rate, not airglow, exhibit a far smaller variation in backgrounds. For the filters where the background is generally dominated by airglow, the backgrounds measured from the data are significantly lower than what the ETC predicts (as of ETC v33.2). The ETC predictions for `average' airglow are greater than the median of our measured background values by factors of 2.51, 2.64, 105, and 3.64, for F115LP, F122M, F125LP, and F140LP, respectively. A preliminary analysis suggests this could be due to certain OI airglow lines usually being fainter than expected by the ETC. With reduced reduced background levels, the shorter-wavelength SBC filters can conduct background-limited observations much more rapidly than had previously been expected. As of ETC v34.1, a new option will be includ
Recent analysis of 23 years of Hubble Space Telescope ACS/SBC data has shown that background levels can vary considerably between observations, with most filters showing over an order of magnitude variation. For the shorter-wavelength filters, the background is understood to be dominated by airglow; however, what precisely drives background variations is not well constrained for any filter. Here, we explore the causes of the background variation. Using over 8,000 archival SBC observations, we developed a machine learning model that can accurately predict the background for an observation, based upon a set of 23 observational parameters. This model indicates that, depending on filter, the SBC background is generally dominated by Solar elevation, Solar separation angle, Earth limb angle of observation, SBC temperature, and target Galactic latitude.
We present a dedicated study of CCD serial ($x$-direction) charge transfer efficiency (CTE) in ACS/WFC. Following past studies of parallel ($y$-direction) CTE, we use the serial CTE trails behind hot pixels in calibration dark frames to characterize charge trapping and release in the serial registers of the WFC detectors. Serial CTE trails are sharper and longer than parallel CTE trails. Many fewer charge traps come into play during serial pixel transfers than parallel transfers, which explains why parallel CTE is much worse than serial CTE. We find that serial CTE can cause losses of $\sim$0.005-0.02~mag in stellar photometry and shift stellar centroids by $\sim$0.01-0.035 pixels. The pixel-based algorithm in CALACS that corrects for parallel CTE losses in WFC data has been modified to include a correction for serial CTE losses. The PCTETAB reference file has also been updated to include serial CTE parameters. The pixel-based correction for serial CTE currently runs only on full-frame WFC images obtained after SM4 (May 2009). Shortly following the publication of this report, science data corrected for both parallel and serial CTE will be available in the MAST archive.
We examined the long-term behavior of the superbias calibration frames for the Advanced Camera for Surveys Wide Field Channel (ACS/WFC) aboard the Hubble Space Telescope (HST). Superbias frames are used to remove detector-level bias structure from science images and are currently generated after an anneal and delivered monthly. The primary goal of this study was to determine whether the frequency of superbias generation could be reduced without compromising calibration quality, potentially aligning with the Wide Field Camera 3 UVIS (WFC3/UVIS) approach of generating only one superbias per year. We analyzed superbias frames produced from 2007 through 2024 to investigate whether these calibration products have changed significantly over time, and whether the frequency of superbias generation and delivery could be safely reduced without loss of calibration accuracy. In addition to visual inspections and pixel-level comparisons, we employed Principal Component Analysis (PCA) to evaluate whether any long-term, global structure exists beneath the apparent noise in these frames. Our findings show that the superbias structure has remained fairly stable post-Servicing Mission 4 (SM4), a 15-
Recently, the ACS team applied an Ubercal framework to assess the photometric repeatability of stars observed across the WFC detector using 15 years of post-SM4 calibration data in the globular cluster 47 Tuc (Ryan et al., 2024). A surprising finding was an apparent 0.05 mag global difference in sensitivity between the WFC1 and WFC2 chips, which had not been seen in prior tests of sensitivity variations around the field-of-view. Given the many degenerate variables within the Ubercal framework such as CTE losses, time-dependent sensitivity, and flat-field corrections, we obtained new calibration data to perform a straightforward test of the reported $\sim$5$\%$ flux offset between detectors. We observed three white dwarf standards with three filters at four positions on the detector (each on a different amplifier), but with the same number of x and y pixel transfers to mitigate differential CTE-related effects. For the F606W and F814W filters, the agreements are good to 0.4$\%$ on average, and always 1$\%$ or better in individual cases. The consistency of these two filters over all three stars and the four dither positions provides very strong evidence against the large global sensi
In quantum information and computation, a central challenge is to determine which quantum states can be transformed into one another under restricted sets of free operations. While many transformations are impossible directly, catalytic processes can enable otherwise forbidden conversions: an auxiliary quantum state (the catalyst) facilitates the transformation while remaining unchanged. In this work, we introduce flexible catalysis, a generalization in which the catalyst is allowed to transform into a different auxiliary state, provided it remains a valid catalyst. We show that this framework subsumes both standard catalytic and multicopy transformations, and we analyze its advantages across several classes of free operations. In particular, we prove that when the free operations are local unitaries or permutation matrices, flexible catalysis enables state extractions that are unattainable with standard catalysis alone.
In the framework of Nambu--Jona-Lasinio model beyond mean field approximation, the effects of pion fluctuations on (inverse) magnetic catalysis and magnetic susceptibility are studied. The negative magnetic susceptibility at low temperature is observed when contributions from both neutral and charged pions are taken into account. In weak field approximation, it is observed that at finite temperature, the magnetic inhibition effect in the chiral limit, resulting from the difference between the transverse and longitudinal velocities of neutral pions, converts to weak magnetic catalysis when considering a non-zero current quark mass. Moreover, the magnetic catalysis is amplified by the charged pions.
Catalysts speed up chemical reactions with no energy input and without being transformed in the process, therefore leaving equilibrium constants unchanged. Some catalysts, however, are much more efficient at accelerating one direction of a reaction. Is it possible for catalysis to be strictly unidirectional, accelerating only one direction of a reaction? Can we observe directional catalysis by analyzing the microscopic trajectory of a single reactant undergoing conversions between a substrate and a product state? We use the framework of a simple but exactly solvable lattice model to study these questions. The model provides examples of strictly one-way catalysts and illustrates a mathematical relationship between the asymmetric transition rates that underlie directional catalysis and the symmetric transition fluxes that underlie chemical equilibrium. The degree of directionality generally depends on the catalytic mechanism and we compare different mechanisms to show how they can obey different scaling laws.
Catalysis, the acceleration of product formation by a substance that is left unchanged, typically results from multiple elementary processes, including diffusion of the reactants toward the catalyst, chemical steps, and release of the products. While efforts to design catalysts are often focused on accelerating the chemical reaction on the catalyst, catalysis is a global property of the catalytic cycle that involves all processes. These are controlled by both intrinsic parameters such as the composition and shape of the catalyst and extrinsic parameters such as the concentration of the chemical species at play. We examine here the conditions that catalysis imposes on the different steps of a reaction cycle and the respective role of intrinsic and extrinsic parameters of the system on the emergence of catalysis by using an approach based on first-passage times. We illustrate this approach for various decompositions of a catalytic cycle into elementary steps, including non-Markovian decompositions, which are useful when the presence and nature of intermediate states are a priori unknown. Our examples cover different types of reactions and clarify the constraints on elementary steps a
The use of ancillary quantum systems known as catalysts is known to be able to enhance the capabilities of entanglement transformations under local operations and classical communication. However, the limits of these advantages have not been determined, and in particular it is not known if such assistance can overcome the known restrictions on asymptotic transformation rates -- notably the existence of bound entangled (undistillable) states. Here we establish a general limitation of entanglement catalysis: we show that catalytic transformations can never allow for the distillation of entanglement from a bound entangled state with positive partial transpose, even if the catalyst may become correlated with the system of interest, and even under permissive choices of free operations. This precludes the possibility that catalysis can make entanglement theory asymptotically reversible. Our methods are based on new asymptotic bounds for the distillable entanglement and entanglement cost assisted by correlated catalysts.
The non-Gaussian operation can be used not only to enhance and distill the entanglement between Gaussian entangled states, but also to improve quantum communications. In this paper, we propose an non-Gaussian continuous-variable quantum key distribution (CVQKD) by using quantum catalysis (QC), which is an intriguing non-Gaussian operation in essence that can be implemented with current technologies. We perform quantum catalysis on both ends of the Einstein-Podolsky-Rosen (EPR) pair prepared by a sender, Alice, and find that for the single-photon QC-CVQKD, the bilateral symmetrical quantum catalysis (BSQC) performs better than the single-side quantum catalysis (SSQC). Attributing to characteristics of integral within an ordered product (IWOP) of operators, we find that the quantum catalysis operation can improve the entanglement property of Gaussian entangled states by enhancing the success probability of non-Gaussian operation, leading to the improvement of the QC-CVQKD system. As a comparison, the QC-CVQKD system involving zero-photon and single-photon quantum catalysis outperforms the previous non-Gaussian CVQKD scheme via photon subtraction in terms of secret key rate, maximal t
We explore the effect of magnetic field on chiral condensation in QCD via a simple bottom up holographic model which inputs QCD dynamics through the running of the anomalous dimension of the quark bilinear. Bottom up holography is a form of effective field theory and we use it to explore the dependence on the coefficients of the two lowest order terms linking the magnetic field and the quark condensate. In the massless theory, we identify a region of parameter space where magnetic catalysis occurs at zero temperature but inverse magnetic catalysis at temperatures of order the thermal phase transition. The model shows similar non-monotonic behaviour in the condensate with B at intermediate T as the lattice data. This behaviour is due to the separation of the meson melting and chiral transitions in the holographic framework. The introduction of quark mass raises the scale of B where inverse catalysis takes over from catalysis until the inverse catalysis lies outside the regime of validity of the effective description leaving just catalysis.
In chemistry, a catalyst is a substance which enables a chemical reaction or increases its rate, while remaining unchanged in the process. Instead of chemical reactions, quantum catalysis enhances our ability to convert quantum states into each other under physical constraints. The nature of the constraints depends on the problem under study and can arise, e.g., from energy preservation. This article reviews the most recent developments in quantum catalysis and gives a historical overview of this research direction. We focus on the catalysis of quantum entanglement and coherence, and also discuss this phenomenon in quantum thermodynamics and general quantum resource theories. We review applications of quantum catalysis and also discuss the recent efforts on universal catalysis, where the quantum state of the catalyst does not depend on the states to be transformed. Catalytic embezzling is also considered, a phenomenon that occurs if the catalyst's state can change in the transition.
We theoretically introduce a new kind of non-Gaussian state-----Laguerre polynomial excited coherent states by using the multiphoton catalysis which actually can be considered as a block comprising photon number operator. It is found that the normalized factor is related to the two-variable Hermite polynomials. We then investigate the nonclassical properties in terms of Mandel's Q parameter, quadrature squeezing, second correlation, and the negativity of Wigner function (WF). It is shown that all these properties are related to the amplitude of coherent state, catalysis number and unbalanced beam splitter (BS). In particular, the maximum degree of squeezing can be enhanced as catalysis number and keeps a constant for single-photon catalysis. In addition, we examine the effect of decoherence by Wigner function, which show that the negative region, characteristic time of decoherence and structure of WF are affected by catalysis number and unbalanced BS. Our work provides a general analysis about how to prepare theoretically polynomials quantum states.
We investigate the QCD phase diagram for nonzero background magnetic fields using first-principles lattice simulations. At the physical point (in terms of quark masses), the thermodynamics of this system is controlled by two opposing effects: magnetic catalysis (enhancement of the quark condensate) at low temperature and inverse magnetic catalysis (reduction of the condensate) in the transition region. While the former is known to be robust and independent of the details of the interactions, inverse catalysis arises as a result of a delicate competition, effective only for light quarks. By performing simulations at different quark masses, we determine the pion mass above which inverse catalysis does not take place in the transition region anymore. Even for pions heavier than this limiting value - where the quark condensate undergoes magnetic catalysis - our results are consistent with the notion that the transition temperature is reduced by the magnetic field. These findings will be useful to guide low-energy models and effective theories of QCD.